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Q.Graphite is a good conductor - explain.
Telangana TsbieTelangana Board of Intermediate Education (Intermediate 1st Year) 2022Subjective· 2mImportance★★★★★
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Start your 14-day free trial to unlock the full solution →In graphite, one electron per carbon atom is left over after sp² bonding and becomes delocalised across each hexagonal layer, giving graphite mobile ("free") electrons that make it electrically conducting, unlike diamond.
Graphite is one of the crystalline allotropes of carbon. In graphite:
- Each carbon atom is sp² hybridised, forming 3 sigma bonds to 3 neighbouring carbon atoms, arranged in flat, hexagonal (honeycomb) layered sheets.
- Each carbon atom has one electron left in an unhybridised p-orbital (perpendicular to the plane of the sheet), which is not used in the sigma-bond framework.
- These leftover p-orbital electrons overlap sideways with each other across the entire hexagonal layer, becoming delocalised over the whole sheet — forming an extended, mobile pi-electron cloud, similar to the delocalisation seen in benzene but spread over the whole 2-D layer. …
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