Q.Write any two uses of Mg metal.
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Alkaline Earth Metals – A First Look
Imagine you are walking through a periodic table. On the far left, you meet the alkali metals — sodium, potassium — soft, violently reactive, almost dangerous. Move one step to the right, and you land on a quieter, more solid family: the alkaline earth metals.
These are the elements of Group 2: beryllium (Be), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), and radium (Ra). Their name comes from an old observation: their oxides (the "earths" of alchemy) dissolve in water to give alkaline (basic) solutions. So they are "earth" that makes alkali.
The Intuition: Why They Are What They Are
Every alkaline earth metal has two electrons in its outermost shell — the ns2 configuration. That pair of electrons is the key to everything.
Think of an atom as a small solar system. The nucleus pulls on the outer electrons. For an alkali metal (Group 1), that pull is relatively weak because there is only one outer electron to hold. Tear that one electron away, and you get a stable +1 ion. For an alkaline earth metal, you have two outer electrons. The nucleus pulls harder on them (higher nuclear charge), and you need more energy to remove both. But once you do, you get a +2 ion — and that +2 charge is very stable because the ion now has a noble-gas electron configuration.
This double-positive charge is the source of their personality. A +2 ion is small and highly charged. It pulls strongly on anything around it — water molecules, other ions, electrons. That is why these metals are harder, denser, and melt at higher temperatures than their Group 1 neighbours. The metallic bond in the solid metal is stronger because each atom contributes two electrons to the "sea" of delocalised electrons, not just one.
The Precise Statement
Alkaline earth metals are the six elements of Group 2 of the periodic table: Be, Mg, Ca, Sr, Ba, Ra. Their general electronic configuration is ns2. They readily lose both valence electrons to form stable +2 cations (M2+). Compared to alkali metals, they are harder, denser, have higher melting points, and are less reactive.
The Pattern in Properties
| Property | Alkali Metals (Group 1) | Alkaline Earth Metals (Group 2) |
|---|---|---|
| Outer electrons | ns1 | ns2 |
| Common ion | M+ | M2+ |
| Hardness | Soft (can be cut with knife) | Harder (Be is very hard) |
| Density | Low (Li, Na float on water) | Higher (Ca sinks) |
| Melting point | Low (Na melts at 98°C) | Higher (Mg melts at 650°C) |
| Reactivity with water | Very vigorous (Na fizzes, K explodes) | Slower (Mg reacts slowly with hot water; Ca reacts steadily) |
Why "Less Reactive"? …
Magnesium is a light, strong metal, which makes it valuable both structurally and for its bright combustion. …
Magnesium is used in light strong alloys (aircraft/auto parts) and in flash powders/fireworks because it burns with a brilliant white light.
Magnesium is a light, reasonably strong metal that burns readily. Its important uses include:
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Making light alloys: Magnesium forms light but strong alloys (for example, magnalium with aluminium) that are used in the construction of aircraft, automobile parts and other places where lightness is important.
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In flash photography, fireworks and incendiary devices: Magnesium burns with an intense, dazzling white light, so it is used in flash powders, fireworks, signal flares and incendiary bombs.
…
- CBSE 2024Set ANNUAL1 markMCQQ.The outer electronic configuration of alkaline earth metal is(a) ns^2(b) ns^1(c) np^6(d) nd^10
›Reveal solutionSolution
Alkaline earth metals have outer configuration ns² (e.g. Mg: [Ne]3s²).
Group 2 elements (Be, Mg, Ca, Sr, Ba, Ra) are called alkaline earth metals. Each has exactly two electrons in its outermost s-orbital and a filled noble-gas core beneath, giving the general valence config …
- CBSE 2022Set sz1 markQ.Both Mg and Ca do not impart any colour to the flame. (True/False)
›Reveal solutionSolution
False. Mg gives no flame colour, but Ca gives a brick-red flame -- so it is not true that 'both' fail to colour the flame.
Alkaline earth metals (Group 2) show flame colouration when their outer electrons are thermally excited in a flame and then fall back to the ground state, emitting visible light of a characteristic wavelength.
- Beryllium and Magnesium do NOT impart any colour to the flame. Their ions (Be2+, Mg2+) are small with high ionisation/excitation energy, so the flame's thermal energy is insufficient to excite their electrons to emit visible light. …
- CBSE 2021Set annual1 markQ.Which is the most abundant alkaline earth metal?
›Reveal solutionSolution
Calcium is the most abundant of the Group 2 (alkaline earth) metals in the earth's crust.
The alkaline earth metals are the Group 2 elements: beryllium, magnesium, calcium, strontium, barium and radium. Ranked by natural abundance in the earth's crust, calcium is the 5th most abundant element overall (about 3.6% by mass), occurring widely as limestone/calcite (CaCO3), gypsum (CaSO4.2H2O) and fluorspar (CaF2). This makes it more abund …
- CBSE 2021Set annual1 markQ.Give reason for the following:(ii) Why do alkaline earth metals have a greater tendency to form complexes as compared to alkali metals?
›Reveal solutionSolution
Higher charge (+2) and smaller size give alkaline earth cations much greater charge density than alkali metal cations, so they bind ligands and form complexes more readily.
Complex formation requires a metal cation to attract and hold electron-pair-donating ligands around itself. How strongly a cation can do this depends on its charge density (charge/size), also called polarising power.
Alkaline earth metals (Group 2) form M^2+ ions that carry twice the positive charge of the corresponding alkali metal's M+ ion (Group 1), while also being smaller in ionic radius than the alkali metal ion of the same period (due to the higher effective nuclear charge across the period). This combination -- higher charge PLUS smaller size -- gives alkaline earth cations a substantially higher charge density than alkali metal cations.
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- CBSE 2021Set annual1 markQ.Give reason for the following:(iii) How does the solubility of hydroxides of alkaline earth metals vary?
›Reveal solutionSolution
Hydroxide solubility of Group 2 metals increases down the group (Be(OH)2 least soluble, Ba(OH)2 most).
For an ionic solid to dissolve, its lattice energy (which holds the ions together in the solid) must be overcome, largely by the hydration energy released as the ions become surrounded by water molecules.
Going down Group 2 (Be -> Mg -> Ca -> Sr -> Ba), the cation size increases steadily. Both lattice energy and hydration energy decrease as ionic size increases, but for these hydroxides, lattice energy falls off FASTER than hydration energy (because the hydroxide ion OH- is relatively small and fixed in size, so the increasing cation size matters more for lattice energy than for the comparatively smaller drop in hydration energy). As a net result, the balance tips increasingly in favour of dissolution as the group is descended, so solubility of the hydroxides increases down the group: Be(OH)2 and Mg(OH)2 are only …
- CBSE 2021Set annual1 markQ.Give reason for the following:(iv) What is slaked lime?
›Reveal solutionSolution
Slaked lime = calcium hydroxide, Ca(OH)2, made by adding water ('slaking') to quicklime (CaO).
Quicklime (calcium oxide, CaO) is produced by strongly heating (calcining) limestone, CaCO3. When water is added to quicklime, an exothermic reaction ('slaking') occurs, producing calcium hydroxide:
CaO(s) + H2O(l) -> Ca(OH)2(s) …
- CBSE 2021Set annual1 markQ.Give reason for the following:(v) Which s-block element is involved in the formation of Grignard's reagent?
›Reveal solutionSolution
Magnesium is the s-block metal used to make Grignard reagents (R-Mg-X).
Grignard reagents are organomagnesium halide compounds of the general formula R-Mg-X (where R is an alkyl or aryl group and X is a halogen, usually Cl, Br or I). They are prepared by reacting an alkyl or aryl halide with magnesium metal turnings in a dry ether solvent (anhydrous conditions are essential, since Grignard reagents react instantly with water/moisture):
R-X + Mg --(dry ether)--> R-Mg-X …
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