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Chemistry · Ch 12 — Surface Chemistry

Catalysis

12.2

Catalysis

Some substances can dramatically change the speed of a reaction without being consumed. Heating potassium chlorate decomposes it only slowly, over 653–873 K:

2KClO3⟶2KCl+3O22KClO_3 \longrightarrow 2KCl + 3O_2

Add a little manganese dioxide and the same decomposition runs much faster and at a lower temperature (473–633 K) — yet the MnO2MnO_2 comes out unchanged in mass and composition.

The systematic study of such effects was begun by Berzelius in 1835, who coined the term catalyst.

  • A catalyst is a substance that accelerates a chemical reaction while itself remaining chemically and quantitatively unchanged afterwards; the phenomenon is catalysis.

Promoters and poisons

  • Promoters enhance a catalyst's activity.
  • Poisons reduce a catalyst's activity. …