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Worked Examples · Example 7.10

Q.Elements of Group 16 generally show lower value of first ionisation enthalpy compared to the corresponding periods of group 15. Why?

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Step 1 — Configurations compared.

Group 15: ns2np3  (half-filled, e.g. N:2s22p3)\text{Group 15: } ns^2np^3 \; (\text{half-filled, e.g. } N: 2s^22p^3)

Group 16: ns2np4  (one p-orbital doubly occupied, e.g. O:2s22p4)\text{Group 16: } ns^2np^4 \; (\text{one p-orbital doubly occupied, e.g. } O: 2s^22p^4)

Step 2 — Stability of half-filled subshell.

A half-filled p-subshell (p3p^3) has each of the three p orbitals singly occupied with parallel spins — this symmetric arrangement has extra exchange stabilisation, making it harder to remove an electron (higher IE1).

Step 3 — Effect of electron pairing in Group 16. …

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