Worked Examples · Example 7.10
Q.Elements of Group 16 generally show lower value of first ionisation enthalpy compared to the corresponding periods of group 15. Why?
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Start your 14-day free trial to unlock the full solution →Step 1 — Configurations compared.
Step 2 — Stability of half-filled subshell.
A half-filled p-subshell () has each of the three p orbitals singly occupied with parallel spins — this symmetric arrangement has extra exchange stabilisation, making it harder to remove an electron (higher IE1).
Step 3 — Effect of electron pairing in Group 16. …
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