Worked Examples · Example 7.18
Q.When HCl reacts with finely powdered iron, it forms ferrous chloride and not ferric chloride. Why?
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Start your 14-day free trial to unlock the full solution →Step 1 — The reaction.
Step 2 — Why only Fe²⁺ forms.
HCl is not an oxidising acid (unlike, say, dilute ); the oxidation of iron here is driven simply by displacement of gas — iron reduces to while itself being oxidised only as far as . Reaching would require a stronger oxidant capable of removing the second (harder-to-remove, more energetically costly) electron from iron.
Step 3 — Confirmation. …
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