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Worked Examples · Example 7.18

Q.When HCl reacts with finely powdered iron, it forms ferrous chloride and not ferric chloride. Why?

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Step 1 — The reaction.

Fe+2HCl→FeCl2+H2↑Fe + 2HCl \rightarrow FeCl_2 + H_2\uparrow

Step 2 — Why only Fe²⁺ forms.

HCl is not an oxidising acid (unlike, say, dilute HNO3HNO_3); the oxidation of iron here is driven simply by displacement of H2H_2 gas — iron reduces H+H^+ to H2H_2 while itself being oxidised only as far as Fe2+Fe^{2+}. Reaching Fe3+Fe^{3+} would require a stronger oxidant capable of removing the second (harder-to-remove, more energetically costly) electron from iron.

Step 3 — Confirmation. …

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