Q.How is chlorine obtained in the laboratory? How does it react with the following?
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Start your 14-day free trial to unlock the full solution →Laboratory chlorine comes from MnO2 + conc. HCl; it disproportionates in cold dilute alkali and oxidizes excess ammonia to nitrogen.
Laboratory preparation of Cl2
Chlorine gas is prepared in the laboratory by heating manganese dioxide (MnO2) with concentrated hydrochloric acid (HCl):
a) Reaction with cold and dilute NaOH
Chlorine undergoes disproportionation (its oxidation state 0 changes to both -1 and +1) with cold, dilute sodium hydroxide to give a mixture of sodium chloride and sodium hypochlorite:
(This solution is used as a bleaching agent, known commercially as 'bleaching solution'.)
b) Reaction with excess NH3 …
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