Q.A microscope using suitable photons is employed to locate an electron in an atom within a distance of 0.1 Å. What is the uncertainty involved in the measurement of its velocity?
The Heisenberg Uncertainty Principle links the uncertainty in position to the uncertainty in momentum. Given , the minimum uncertainty in velocity is .
The core idea here is the Heisenberg Uncertainty Principle — one of the most fundamental results in quantum mechanics. It says that you cannot simultaneously know both the position and the momentum of a particle with perfect precision. The more precisely you pin down where it is, the less precisely you can know how fast it's moving (and in which direction).
In this problem, a microscope "locates" an electron within a distance of . That is the uncertainty in position, . The principle then forces a minimum uncertainty in the electron's momentum, , and from that we can find the uncertainty in velocity, .
Let's walk through it step by step.
- State the Uncertainty Principle The Heisenberg Uncertainty Principle for position and momentum is:
where is Planck's constant ().
The sign means the product of the uncertainties can never be smaller than that value — it's a fundamental lower bound.
- Convert the given position uncertainty to metres The problem gives . Remember: . So:
- Find the minimum uncertainty in momentum To get the smallest possible , we take the equality case of the principle:
Plug in the numbers:
First, .
Then:
Divide:
- Relate momentum uncertainty to velocity uncertainty For an electron, momentum , where is the electron's mass (). Since the mass is known precisely, the uncertainty in momentum is directly related to the uncertainty in velocity:
Substitute:
That gives:
- Interpret the result This is a huge speed — about 2% of the speed of light. It tells you that if you try to pin an electron's position down to the size of an atom (0.1 Å is roughly the diameter of a hydrogen atom), you lose almost all knowledge of its velocity. The electron could be moving anywhere from nearly stationary to millions of metres per second.
A common mistake is to forget that must be in metres, not angstroms. Also, some students use (the simpler form from some textbooks), but the correct quantum mechanical lower bound is . Using would give an answer about 12 times smaller — still large, but wrong for this standard formulation.
Notice that the uncertainty in velocity is enormous compared to everyday speeds. This is why we can't talk about electrons "orbiting" like planets — the uncertainty principle smears out any definite path.
The minimum uncertainty in the electron's velocity is approximately .
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