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NCERT Exemplar · Q52

Q.Threshold frequency, ν0 is the minimum frequency which a photon must possess to eject an electron from a metal. It is different for different metals. When a photon of frequency 1.0×10^15 s^-1 was allowed to hit a metal surface, an electron having 1.988 × 10^-19 J of kinetic energy was emitted. Calculate the threshold frequency of this metal. Show that an electron will not be emitted if a photon with a wavelength equal to 600 nm hits the metal surface.

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The photoelectric effect equation KE=hν−hν0KE = h\nu - h\nu_0 gives the threshold frequency. For the given data, ν0=7.0×1014 s−1\nu_0 = 7.0 \times 10^{14} \text{ s}^{-1}. A 600 nm photon has frequency 5.0×1014 s−15.0 \times 10^{14} \text{ s}^{-1}, which is below threshold, so no emission occurs.

The photoelectric effect is a clean demonstration of quantum energy transfer. A photon delivers its entire energy hνh\nu to an electron. Part of that energy goes into overcoming the binding force that holds the electron in the metal — that's the work function W=hν0W = h\nu_0. The leftover energy appears as the electron's kinetic energy. So the equation is simply energy conservation at the quantum level:

KE=hν−hν0KE = h\nu - h\nu_0

We know h=6.626×10−34 J⋅sh = 6.626 \times 10^{-34} \text{ J·s}, a universal constant. The threshold frequency ν0\nu_0 is what we need — the minimum frequency for which the photon energy just equals the work function, giving zero kinetic energy.

  1. Write the photoelectric equation and substitute known values. The kinetic energy is 1.988×10−19 J1.988 \times 10^{-19} \text{ J}, the incident frequency is ν=1.0×1015 s−1\nu = 1.0 \times 10^{15} \text{ s}^{-1}, and Planck's constant h=6.626×10−34 J⋅sh = 6.626 \times 10^{-34} \text{ J·s}. So:

1.988×10−19=(6.626×10−34)(1.0×1015)−(6.626×10−34)ν01.988 \times 10^{-19} = (6.626 \times 10^{-34})(1.0 \times 10^{15}) - (6.626 \times 10^{-34})\nu_0

  1. Calculate the incident photon energy.

hν=(6.626×10−34)(1.0×1015)=6.626×10−19 Jh\nu = (6.626 \times 10^{-34})(1.0 \times 10^{15}) = 6.626 \times 10^{-19} \text{ J}

  1. Solve for ν0\nu_0. Rearranging the equation:

hν0=hν−KE=6.626×10−19−1.988×10−19=4.638×10−19 Jh\nu_0 = h\nu - KE = 6.626 \times 10^{-19} - 1.988 \times 10^{-19} = 4.638 \times 10^{-19} \text{ J}

Then:

ν0=4.638×10−196.626×10−34=7.0×1014 s−1\nu_0 = \frac{4.638 \times 10^{-19}}{6.626 \times 10^{-34}} = 7.0 \times 10^{14} \text{ s}^{-1}

Tip

Notice that 1.988×10−191.988 \times 10^{-19} is very close to 0.3×6.626×10−190.3 \times 6.626 \times 10^{-19}, so the threshold energy is 0.7×hν0.7 \times h\nu — a quick mental check that ν0=0.7×1015=7×1014\nu_0 = 0.7 \times 10^{15} = 7 \times 10^{14}.

  1. Now check the 600 nm photon. …

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