Physics · Ch 3 — Current Electricity
Temperature Dependence of Resistivity
Temperature Dependence of Resistivity
Why Does Resistivity Change with Temperature?
Resistivity () is not a fixed property of a material — it changes with temperature. The way it changes depends on the type of material: metals, alloys, and semiconductors behave differently. The physical reason lies in the microscopic picture of current flow.
The Approximate Linear Relation (for Metals)
Over a limited range of temperature (not too large), the resistivity of a metallic conductor follows a simple linear law. If you know the resistivity at some reference temperature , then the resistivity at another temperature is given by:
- = resistivity at temperature
- = resistivity at reference temperature
- = temperature coefficient of resistivity (unit: or )
- = change in temperature
For metals, is positive — resistivity increases as temperature rises.
Important: This formula gives a straight line when is plotted against , but it is only an approximation. At very low temperatures (much below ), the graph deviates significantly from a straight line.
Special Materials: Alloys with Weak Temperature Dependence
Some alloys show a very weak dependence of resistivity on temperature. Examples include:
- Nichrome (nickel, iron, chromium)
- Manganin
- Constantan
Because their resistance changes very little with temperature, these materials are used to make wire-bound standard resistors — components that need a stable, predictable resistance.
The Opposite Behaviour: Semiconductors
Unlike metals, the resistivity of semiconductors decreases as temperature increases. This is the opposite of what metals do.
Physical Explanation: Why Does This Happen?
The resistivity formula derived earlier is:
Where:
- = mass of electron
- = number of free electrons per unit volume
- = charge of electron
- = average time between collisions (relaxation time)
Resistivity depends on two key factors:
- — the density of charge carriers
- — how long electrons travel before colliding
In Metals: …
Drawn by us to help you understand the concept clearly, and verified to make sure it's accurate. For exams, practice from your textbook's own diagram.
The graph plots resistivity (in units of ) on the vertical axis against absolute temperature (in kelvin) on the horizontal axis. The vertical axis is marked at and (i.e., and ). The horizontal axis has ticks at , , , and K.
The curve begins near the origin at very low temperatures and rises with an upward-concave (parabola-like) shape. By K, the resistivity climbs steeply toward . This shows that resistivity increases with temperature for copper, but the increase is not linear over the entire range — especially at very low temperatures, the graph deviates from a straight line.
Physical idea: Over a limited range of temperatures (not too large), the resistivity of a metallic conductor follows the approximate linear relation:
where:
- = resistivity at temperature ,
- = resistivity at a reference temperature ,
- = temperature coefficient of resistivity (units: or ).
For metals, is positive, meaning resistivity rises with temperature. However, at temperatures much lower than (i.e., below about 273 K), the graph deviates considerably from a straight line — as Fig. 3.8 shows with its curved shape near the origin. The linear formula is therefore only an approximation valid over a limited range around any chosen . …
Drawn by us to help you understand the concept clearly, and verified to make sure it's accurate. For exams, practice from your textbook's own diagram.
The graph plots resistivity (in units of ) on the vertical axis against absolute temperature (in kelvin) on the horizontal axis. The vertical scale runs from to , and the horizontal scale from to .
The data form a nearly straight line with a gentle positive slope. At low temperatures (near ) the resistivity is about , rising to about at . This weak, almost-linear increase contrasts sharply with the curved plot for copper shown in the textbook’s Fig. 3.8.
Physical idea: Nichrome is an alloy (nickel, iron, chromium) whose resistivity changes very little with temperature. This makes it ideal for wire-wound standard resistors and heating elements, because its resistance remains nearly constant over a wide temperature range.
Key formula developed with this figure is the linear approximation for resistivity over a limited temperature range:
- = resistivity at temperature
- = resistivity at reference temperature
- = temperature coefficient of resistivity (units: or ) …
Drawn by us to help you understand the concept clearly, and verified to make sure it's accurate. For exams, practice from your textbook's own diagram.
What the Graph Shows
The figure is a first-quadrant plot with resistivity on the vertical axis and temperature on the horizontal axis. There are no numeric ticks — it is a schematic (conceptual) graph.
The curve begins at a high value of when is small (near the vertical axis). As increases, the curve falls steeply, then gradually flattens out and approaches the -axis asymptotically. The shape is that of an exponential decay: resistivity decreases rapidly at first, then more slowly, and eventually tends toward a very low, nearly constant value.
The Physical Idea
This graph illustrates the opposite behaviour of semiconductors compared to metals. For metals, resistivity increases with temperature (positive temperature coefficient). For semiconductors, resistivity decreases with temperature (negative temperature coefficient).
The reason lies in the number of charge carriers . In a semiconductor, raising the temperature dramatically increases — more electrons break free from their bonds and become available for conduction. This increase in more than compensates for the decrease in the average collision time (which also occurs because electrons move faster). The net effect is that drops sharply.
The Key Formula
The textbook derives resistivity from the relation:
where:
- = mass of an electron
- = number of free electrons per unit volume …