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Chemistry · Ch 3 — Classification of Elements and Periodicity in Properties

Electronic Configurations and Types of Elements: s-, p-, d-, f-Blocks

3.6

Electronic Configurations and Types of Elements: s-, p-, d-, f-Blocks

From Electronic Configuration to Four Blocks

The Aufbau principle and each element's electronic configuration give a solid theoretical footing for periodic classification. Elements in the same vertical column of the Periodic Table share the same outer-shell electronic configuration, which is exactly why elements within a group show similar chemical behaviour.

Building on this idea, every element in the Periodic Table can be sorted into one of four blocks — s, p, d, or f — according to which sub-shell its highest-energy (differentiating) electron enters. Fig. 3.3 marks out this division, and also overlays a second, independent classification: metals, non-metals, and metalloids.

Figure 3.3Types of elements (s-, p-, d-, f-blocks) in the Periodic Table based on the orbitals being filled; also metals, non-metals and metalloids.
Fig. 3.3 — Types of elements (s-, p-, d-, f-blocks) in the Periodic Table based on the orbitals being filled; also metals, non-metals and metalloids.

Drawn by us to help you understand the concept clearly, and verified to make sure it's accurate. For exams, practice from your textbook's own diagram.

Fig. 3.3 draws the periodic table as four separate block panels, one per type of orbital being filled — exactly how the book prints it:

  • s-BLOCK (groups 1–2): the alkali and alkaline earth metals, rows 2s2s to 7s7s (Li/Be down to Fr/Ra). Hydrogen sits in its own detached 1s1s cell — it belongs to no block-panel, reflecting its unique position.
  • d-BLOCK (groups 3–12): the four transition series, rows 3d3d (Sc–Zn) to 6d6d (Ac–Cn). All metals.
  • p-BLOCK (groups 13–18): rows 2p2p to 7p7p, with helium placed at the top of group 18 despite its 1s21s^2 configuration.
  • f-BLOCK: the lanthanoids (4f4f, Ce–Lu) and actinoids (5f5f, Th–Lr) as two separate strips.

Overlaid on the block structure is the figure's second classification, by colour: metals, non-metals and metalloids. The metalloid cells in the figure are Si, Ge, As, Sb, Te, Po and At — the staircase zone between metals and non-metals in the p-block. (The chapter text's own list in Section 3.6.5 names Si, Ge, As, Sb and Te; the figure additionally shades Po and At. Boron is coloured as a non-metal in the figure.) The non-metals cluster in the upper right of the p-block — H, C, N, O, F, P, S, Cl, Se, Br, I — and the noble gases (He–Og) carry their own shade. Everything to the left and below — the entire s, d and f blocks plus Al, Ga, In, Sn, Tl, Pb, Bi and the 7p7p metals — is metallic.

Important

The block tells you which subshell receives the last electron (the basis of Section 3.6's classification); the colour tells you the broad chemical character. Metallic character strengthens toward the lower left, non-metallic toward the upper right, and the metalloids straddle the divide — which is why silicon and germanium behave as semiconductors. …

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