Q.A cubic unit cell of cesium chloride (CsCl) has cesium atoms situated at the eight corners of a cube of side , and a chlorine atom situated at the centre of the cube. Each Cs atom is deficient by one electron, so it carries a charge ; the Cl atom carries one excess electron, so it carries a charge .
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Start your 14-day free trial to unlock the full solution →Because the eight Cs charges sit at corners that pair up diametrically across the centre, their fields at the Cl atom cancel and the net field is zero. When one Cs is removed, the remaining seven give a net force equal in magnitude and opposite in direction to the force the removed charge alone would have exerted — about N, pointing away from the missing corner.
(i) Net field at Cl
The eight corners occur in four pairs, each pair lying on a body diagonal on opposite sides of the centre and equidistant from it. The two Cs of a pair produce equal and opposite fields at the centre, which cancel. Summing over the four pairs:
(ii) Net force after removing the corner charge at A
Use superposition. With all eight present the force on Cl is zero:
So the seven remaining charges give a force equal and opposite to the force that the removed Cs at A exerted on Cl. Since Cs attracted the Cl toward A, points away from A (along the body diagonal, toward the diagonally opposite corner). Equivalently, removing a is like adding a at A, which repels the Cl.
Magnitude. The corner-to-centre distance is half the body diagonal: …
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