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Exercise · Q6

Q.State, with reasons based on oxidation-number change, whether each of the following is a redox reaction:

(a) NaCl(aq)+AgNO3(aq)→AgCl(s)+NaNO3(aq)\text{NaCl}(aq) + \text{AgNO}_3(aq) \to \text{AgCl}(s) + \text{NaNO}_3(aq),
(b) Zn(s)+2HCl(aq)→ZnCl2(aq)+H2(g)\text{Zn}(s) + 2\text{HCl}(aq) \to \text{ZnCl}_2(aq) + \text{H}_2(g).
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(a) In NaCl(aq)+AgNO3(aq)→AgCl(s)+NaNO3(aq)\text{NaCl}(aq) + \text{AgNO}_3(aq) \to \text{AgCl}(s) + \text{NaNO}_3(aq), assign oxidation numbers: Na is +1+1 on both sides, Cl is −1-1 on both sides, Ag is +1+1 on both sides, and the NO3−\text{NO}_3^- group is unchanged throughout. No atom changes oxidation number anywhere in this equation — it is simply an ion-exchange (double-displacement/precipitation) reaction, so it is not a redox reaction.\n\n(b) In Zn(s)+2HCl(aq)→ZnCl2(aq)+H2(g)\text{Zn}(s) + 2\text{HCl}(aq) \to \text{ZnCl}_2(aq) + \text{H}_2(g), zinc goes from oxidation number 00 (free element) to +2+2 in ZnCl2\text{ZnCl}_2 — oxidation. Hydrogen goes from +1+1 (in HCl) to 00 (free H2\text{H}_2 gas) — reduction. Since two elements change oxidation number in a paired, compensating way, this is a redox reaction (zinc is the reducing agent, H+\text{H}^+ from HCl is the oxidizing agent). [!ANSWER] (a) NaCl+AgNO3→AgCl+NaNO3\text{NaCl}+\text{AgNO}_3\to\text{AgCl}+\text{NaNO}_3 is NOT a redox reaction (no oxidation number changes); (b) Zn+2HCl→ZnCl2+H2\text{Zn}+2\text{HCl}\to\text{ZnCl}_2+\text{H}_2 IS a redox reaction (Zn: 0→+20\to+2; H: +1→0+1\to0).

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