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Exercise · Q14

Q.Show that 2Cu+→Cu+Cu2+2\text{Cu}^{+} \to \text{Cu} + \text{Cu}^{2+} is a disproportionation reaction by tracking the oxidation number of copper on both sides.

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In 2Cu+→Cu+Cu2+2\text{Cu}^{+} \to \text{Cu} + \text{Cu}^{2+}, copper starts uniformly at oxidation number +1+1 in Cu+\text{Cu}^{+}. In the products, one copper atom is present as metallic Cu\text{Cu} (oxidation number 00 — a decrease from +1+1, so this atom is reduced), and the other is present as Cu2+\text{Cu}^{2+} (oxidation number +2+2 — an increase from +1+1, so this atom is oxidized). Because the single starting species Cu+\text{Cu}^{+} produces one product at a lower oxidation number and one at a higher oxidation number, this reaction fits the definition of disproportionation exactly. Balancing the electron count confirms it is self-consistent: the reduced copper gains 1 electron, and the oxidized copper loses 1 electro …

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