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Physics · Ch 12 — Atoms

Radii of the Bohr Orbits

12.4.1

Radii of the Bohr Orbits

Setting up the two conditions together. Section 1.4 gave two conditions that any allowed Bohr orbit of a hydrogen-like atom (nuclear charge +Ze+Ze, one orbiting electron) must simultaneously satisfy: the force-balance condition (Postulate 1) and the angular-momentum quantisation condition (Postulate 2). Solving these two equations together, for a given nn, pins down the exact radius rnr_n of that orbit.

From the force-balance condition:

14πϵ0⋅Ze2r2=mv2r⟹v2=Ze24πϵ0 m r\frac{1}{4\pi\epsilon_0}\cdot\frac{Ze^2}{r^2} = \frac{mv^2}{r} \quad\Longrightarrow\quad v^2 = \frac{Ze^2}{4\pi\epsilon_0\,m\,r}

From the quantisation condition, mvr=nh/2πmvr=nh/2\pi, so v=nh2πmrv = \dfrac{nh}{2\pi m r}, and hence

v2=n2h24π2m2r2v^2 = \frac{n^2h^2}{4\pi^2m^2r^2}

Combining the two expressions for v2v^2:

n2h24π2m2r2=Ze24πϵ0 m r⟹n2h24π2mr=Ze24πϵ0⟹r=ϵ0n2h2πmZe2\frac{n^2h^2}{4\pi^2m^2r^2} = \frac{Ze^2}{4\pi\epsilon_0\,m\,r} \quad\Longrightarrow\quad \frac{n^2h^2}{4\pi^2mr} = \frac{Ze^2}{4\pi\epsilon_0} \quad\Longrightarrow\quad r = \frac{\epsilon_0n^2h^2}{\pi m Ze^2}

So the radius of the nnth permitted orbit of a hydrogen-like atom of atomic number ZZ is

rn=ϵ0n2h2πmZe2\boxed{r_n = \frac{\epsilon_0 n^2h^2}{\pi m Z e^2}}

Numerical value and the Bohr radius. Substituting the known values of ϵ0\epsilon_0, hh, mm (electron mass) and ee for the case Z=1Z=1, n=1n=1 (the innermost orbit of ordinary hydrogen) gives r1=0.529×10−10 m=0.529r_1 = 0.529\times10^{-10}\ \text{m} = 0.529 Å (Numerical 1 carries out this substitution in full). This particular value is called the Bohr radius, usually written a0a_0, and it sets the natural size scale for the hydrogen atom. Since rn∝n2/Zr_n\propto n^2/Z, every other allowed orbit's radius can be written directly in terms of it:

rn=0.529 n2Z A˚(hydrogen: rn=n2a0)r_n = \frac{0.529\,n^2}{Z}\ \text{Å} \qquad \text{(hydrogen: } r_n = n^2a_0\text{)} …