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Intext · Q5

Q.Following type of non-ionic detergents are present in liquid detergents, emulsifying agents and wetting agents. Label the hydrophilic and hydrophobic parts in the molecule. Identify the functional group(s) present in the molecule.
C9H19-C6H4-O(CH2CH2O)xCH2CH2OH (x = 5 to 10)

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In a detergent molecule, the hydrophobic (water-repelling) part is a non-polar hydrocarbon portion with no affinity for water, while the hydrophilic (water-attracting) part is polar and can hydrogen-bond with water.

For C9H19−C6H4−O(CH2CH2O)xCH2CH2OHC_9H_{19}-C_6H_4-O(CH_2CH_2O)_xCH_2CH_2OH:

  • Hydrophobic part: C9H19−C6H4−C_9H_{19}-C_6H_4- — a nonyl (C9) hydrocarbon chain attached to a benzene ring. Being a hydrocarbon/aromatic group, it is non-polar and water-insoluble.
  • Hydrophilic part: −O(CH2CH2O)xCH2CH2OH-O(CH_2CH_2O)_xCH_2CH_2OH — the repeating polyethylene oxide chain terminating in a free −OH-OH group. The several ether oxygens along the chain and the terminal hydroxyl group can form hydrogen bonds with water, making this part water-soluble.
  • Functional groups present: ether linkages (−O−-O-, repeated x+1 times within the chain) and one terminal alcohol (−OH-OH) group. …

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