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Intext · Q4

Q.In Haber's process, hydrogen is obtained by reacting methane with steam in presence of NiO as catalyst. The process is known as steam reforming. Why is it necessary to remove CO when ammonia is obtained by Haber's process?

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Step 1 – Where CO comes from. Steam reforming of methane, CH4+H2O→NiOCO+3H2CH_4 + H_2O \xrightarrow{NiO} CO + 3H_2, produces hydrogen along with carbon monoxide.

Step 2 – The ammonia step needs a clean catalyst. Ammonia is synthesised as

N2(g)+3H2(g)⇌Fe catalyst2NH3(g)N_2(g) + 3H_2(g) \underset{\text{Fe catalyst}}{\rightleftharpoons} 2NH_3(g)

over a finely divided iron catalyst (promoted with MoMo/K2OK_2O/Al2O3Al_2O_3). …

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