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NCERT Exemplar · Q22

Q.Express unified atomic mass unit in kg.

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The unified atomic mass unit is defined as exactly one-twelfth the mass of a carbon-12 atom; converting through Avogadro's number gives u=1.66054×10−27u = 1.66054 \times 10^{-27} kg.

The unified atomic mass unit (uu, sometimes written as amu or dalton) is the standard unit for expressing atomic and molecular masses. It provides a convenient scale because atomic masses in uu are close to their mass numbers, making calculations in chemistry and nuclear physics far more intuitive than working with kilograms directly.

The definition is precise: one unified atomic mass unit is exactly 112\frac{1}{12} of the mass of a single neutral carbon-12 atom in its ground state. This choice anchors the atomic mass scale to a stable, abundant isotope.

Converting uu to kilograms

The conversion hinges on two experimentally determined constants: the molar mass of carbon-12 and Avogadro's number.

1. Start with the molar mass of carbon-12

By definition, the molar mass of 12C^{12}\text{C} is exactly 12 g/mol=0.012 kg/mol12 \text{ g/mol} = 0.012 \text{ kg/mol}. This means one mole of carbon-12 atoms has a mass of exactly 1212 grams.

2. Relate molar mass to individual atomic mass

One mole contains Avogadro's number of atoms:

NA=6.02214076×1023 mol−1N_A = 6.02214076 \times 10^{23} \text{ mol}^{-1}

Therefore, the mass of a single carbon-12 atom is:

m12C=0.012 kg6.02214076×1023=1.99265×10−26 kgm_{^{12}\text{C}} = \frac{0.012 \text{ kg}}{6.02214076 \times 10^{23}} = 1.99265 \times 10^{-26} \text{ kg}

3. Apply the definition of the unified atomic mass unit

Since 1 u=112m12C1 \, u = \frac{1}{12} m_{^{12}\text{C}}, we have:

u=1.99265×10−2612=1.66054×10−27 kgu = \frac{1.99265 \times 10^{-26}}{12} = 1.66054 \times 10^{-27} \text{ kg} …

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