Q.The Sun is a hot plasma (ionized matter) with its inner core at a temperature exceeding 107 K, and its outer surface at a temperature of about 6000 K. At these high temperatures, no substance remains in a solid or liquid phase. In what range do you expect the mass density of the Sun to be, in the range of densities of solids and liquids or gases? Check if your guess is correct from the following data: mass of the Sun =2.0×1030 kg, radius of the Sun =7.0×108 m.
🔒You're viewing a preview — the full solution, concept, methods & PYQ mapping are locked.
🔒 Start your 14-day free trial to unlock the full solution →Concept understanding — Atomic Volume Calculation
Atomic Volume: Meaning and Calculation
Atoms are mostly empty space — a tiny dense nucleus wrapped in a fuzzy electron cloud. So "atomic volume" does not mean the volume of a solid ball; it means the average space one atom occupies when many atoms are packed together in a solid or liquid.
Think of a crowded hall: to find the space per person you divide the hall's volume by the number of people. Atomic volume does exactly that for atoms.
Definition
Atomic volume is the volume occupied by one mole of atoms of an element in its solid or liquid state. It is found from the element's molar mass and density:
Vatomic=ρM
- Vatomic = atomic volume (cm³/mol)
- M = molar mass (g/mol)
- ρ = density (g/cm³)
This gives the volume per mole. Dividing by Avogadro's number gives the space per single atom:
Vone atom=NAVatomic,NA=6.022×1023 mol−1
Worked example — aluminium
Molar mass M=26.98 g/mol, density ρ=2.70 g/cm³:
Vatomic=2.7026.98=9.99 cm3/mol
So one mole of Al atoms occupies about 10 cm³. Per atom:
Vone Al atom=6.022×10239.99=1.66×10−23 cm3
Periodic trends
- Down a group: atomic volume increases — more electron shells make atoms larger.
- Across a period: it generally decreases — rising nuclear charge pulls the electrons in tighter.
- Allotropes differ: diamond is denser than graphite, so diamond's atomic volume is smaller, though both are carbon.
These trends help explain why alkali metals (large atomic volume) are soft and reactive, while transition metals (smaller atomic volume) are hard and dense. …
Why this formula?
Atomic Volume Calculation: Understanding the "Why" Behind the Formula
What Is Atomic Volume?
Atomic volume is not the volume of a single atom — it's the volume occupied by one mole of atoms of an element in its solid state. This is a macroscopic quantity that helps us understand how tightly atoms pack together.
The key formula is:
Atomic Volume=DensityAtomic Mass
Let's break down why this works.
The Core Reasoning: From Mass to Volume
Step 1: What does density tell us?
Density (ρ) is defined as:
ρ=VolumeMass
For a pure solid element, if we take one mole of atoms:
- Mass of one mole = Atomic mass (in g/mol)
- Volume of one mole = Atomic volume (in cm³/mol)
So:
ρ=Atomic volumeAtomic mass
Step 2: Rearranging to find atomic volume
Volume=DensityMass
Therefore:
Atomic Volume=DensityAtomic Mass
Why This Makes Physical Sense
Atomic mass tells you how heavy one mole of atoms is; density tells you how much mass fits in a given space. Dividing mass by density gives the space that mass occupies.
Example intuition: If iron has atomic mass ≈ 56 g/mol and density 7.87 g/cm³, then:
Atomic volume=7.8756≈7.1 cm3/mol
This means one mole of iron atoms (about 6.022×1023 atoms) occupies roughly 7.1 cm³ of space.
Important Exam Points
| Concept | Why It Matters |
|---|---|
| Units | Atomic mass in g/mol, density in g/cm³ → atomic volume in cm³/mol |
| Solid state only | The formula assumes atoms are closely packed; gases/liquids have different packing |
V=34πR3=34π(7.0×108)3≈1.44×1027 m3
ρ=VM=1.44×10272.0×1030≈1.4×103 kg/m3 …
Dividing the Sun's mass by its volume gives an average density of about 1.4×103 kg/m3 — comparable to water, in the range of liquids and solids, not gases, even though the Sun is entirely plasma.
Why "hot plasma" doesn't automatically mean "low density"
It's tempting to guess that because the Sun is a superheated, ionized gas, its density should resemble ordinary gases (of order 1 kg/m3). But density depends on pressure, not just temperature — and the core of the Sun is compressed by its own enormous gravity to a pressure of hundreds of billions of atmospheres. Let's check the guess against the actual numbers.
Computing the average density
ρ=VM,V=34πR3
Given: M=2.0×1030 kg, R=7.0×108 m.
- Volume:
R3=(7.0×108)3=343×1024=3.43×1026 m3
V=34π×3.43×1026≈1.44×1027 m3
- Density:
ρ=1.44×10272.0×1030≈1.4×103 kg/m3
Interpreting the result …
Method: Density Estimation from Mass and Volume
This method uses the definition of average density — the ratio of total mass to total volume — to classify the Sun’s state of matter.
Steps
- Recall the formula for average density The average density ρ of any object is:
ρ=volumemass
- Calculate the volume of the Sun Assume the Sun is a sphere. Volume of a sphere of radius R:
V=34πR3
Given R=7.0×108 m:
V=34π(7.0×108)3
First compute R3:
(7.0×108)3=343×1024=3.43×1026 m3
Then:
V=34×3.14×3.43×1026≈1.44×1027 m3
- Compute the average density Mass M=2.0×1030 kg:
ρ=1.44×10272.0×1030≈1.39×103 kg/m3
- Interpret the result
- Density of water: 103 kg/m3
- Typical solids/liquids: 103 to 104 kg/m3
- Gases at STP: ≈1 kg/m3 …
Common Mistakes in Atomic Volume / Density Calculation (Sun Problem)
Students often make predictable errors when solving this NCERT/competitive exam problem. Here are the most frequent ones and how to avoid each:
1. ✗ Using wrong formula for volume of a sphere
Mistake: Using V=πr2 (area) or V=34πr2 (missing one power of r).
How to avoid: Memorise the exact formula:
V=34πr3
Always write it down before substituting numbers. Double-check the exponent on r.
2. ✗ Forgetting to cube the radius correctly
Mistake: Computing r3 as 7.0×1024 instead of 7.03×1024=343×1024.
How to avoid:
- Cube the coefficient and the power of 10 separately:
(7.0×108)3=7.03×(108)3=343×1024
- Write intermediate steps — don’t skip directly to the final number.
3. ✗ Mixing up units (km vs m)
Mistake: Using radius in km (7.0×105 km) but mass in kg, leading to density off by 109.
How to avoid:
- Always convert to SI units before calculation.
- Given radius is already in metres (7.0×108 m) — confirm this before proceeding.
4. ✗ Arithmetic errors in powers of 10
Mistake: Getting 1030/1024=106 instead of 1030/1025=105 (if volume exponent is wrong).
How to avoid:
-
Compute volume exponent carefully:
r3→(108)3=1024, then multiply by 34π≈4.19 → exponent stays 1024 (coefficient ~4.19).
-
So V≈4.19×1024×103? No — careful: r=7.0×108, so r3=343×1024=3.43×1026.
Then V=34π×3.43×1026≈1.44×1027 m3.
-
Then density:
ρ=1.44×10272.0×1030≈1.39×103 kg/m3
5. ✗ Not comparing with known density ranges
Mistake: Computing ρ≈1400 kg/m3 but not knowing what it means.
How to avoid: Memorise reference values:
- Gases: ∼1 kg/m3 (air at STP)
- Liquids: ∼1000 kg/m3 (water)
- Solids: ∼2000−8000 kg/m3 …
- KCET 2024Set D-21 markMCQQ.The ratio of volume of Al27 nucleus to its surface area is (Given R0=1.2×10−15 m ) (A) 2.1×10−15 m (B) 1.3×10−15 m (C) 0.22×10−15 m (D) 1.2×10−15 m
›Reveal solutionSolution
The ratio of volume to surface area for any spherical nucleus is R/3, where R=R0A1/3. For Al27, A=27, so R=1.2×10−15×3=3.6×10−15 m, giving a ratio of 1.2×10−15 m. The correct option is (D).
The key idea here is that a nucleus is modeled as a uniform sphere. For any sphere, the ratio of volume to surface area is simply R/3 — a clean geometric fact. Once you know the nuclear radius formula, the rest is arithmetic.
The nuclear radius is given by R=R0A1/3, where R0=1.2×10−15 m and A is the mass number. For Al27, A=27, so A1/3=3. That gives R=1.2×10−15×3=3.6×10−15 m.
Now, for a sphere:
- Volume V=34πR3
- Surface area S=4πR2
The ratio SV=4πR234πR3=3R.
So the ratio is simply 33.6×10−15=1.2×10−15 m. …
- TG EAPCET 2023Set ap-2023-05-10-AN1 markMCQQ.The Van der Waal’s equation for the gases is given by (P+V2a)(V−b)=RT where P is pressure; V is volume; T is absolute temperature; R universal gas constant and a, b are constants. The dimensional formula of (RTab) is (A) [ML5T−2] (B) [M0L0T0] (C) [ML−1T−2] (D) [M0L6T0]
›Reveal solutionSolution
The key is to find the dimensions of a and b separately from the Van der Waals equation, then combine them with RT to get the dimensions of RTab. The result is [M0L6T0], which is option (D).
The Van der Waals equation corrects the ideal gas law for real gas behaviour. The term V2a accounts for intermolecular attraction, and b accounts for the finite volume of molecules. Because the equation is dimensionally consistent, we can extract the dimensions of a and b by looking at how they appear.
-
Find the dimensions of b.
In the term (V−b), we subtract b from V. Only quantities with the same dimensions can be added or subtracted. So b must have the same dimensions as volume V.
Volume has dimensions [L3].
Hence, [b]=[L3].
-
Find the dimensions of a.
Look at the term (P+V2a). Again, P and V2a must have the same dimensions because they are added.
Pressure P has dimensions [ML−1T−2] (force per unit area).
So [V2a]=[ML−1T−2].
Since [V2]=[L6], we get [a]=[ML−1T−2]×[L6]=[ML5T−2].
-
Find the dimensions of RT.
From the ideal gas law PV=nRT, for one mole (n=1) we have PV=RT.
So [RT]=[P][V]=[ML−1T−2]×[L3]=[ML2T−2].
This is the same as energy (work), which makes sense — RT is energy per mole.
-
Combine to get RTab.
Now put the dimensions together:
[ab]=[a][b]=[ML5T−2]×[L3]=[ML8T−2]. …
-
- TG EAPCET 2023Set ap-2023-05-11-AN1 markMCQQ.The half-life period of an artificial radioactive substance is 10 days. The time taken for the activity of the substance to reduce to 1% of its initial activity (in days) is (loge10=2.303) (A) 990 (B) 70.5 (C) 66.5 (D) 46
›Reveal solutionSolution
Radioactive decay follows an exponential law governed by the half-life. Using the relation between activity and time, we find that reducing to 1% of initial activity requires approximately 66.5 days.
The activity of a radioactive substance measures how many nuclei decay per unit time. Because decay is a random process governed by probability, the activity decreases exponentially with a characteristic time scale set by the half-life.
The key insight is that after each half-life period, exactly half of the remaining active nuclei have decayed. So if we want the activity to drop to some small fraction like 1%, we need to count how many half-lives fit into that reduction.
The mathematical relationship is:
A(t)=A0(21)t/T1/2
where A(t) is the activity at time t, A0 is the initial activity, and T1/2 is the half-life.
Alternatively, using the decay constant λ=T1/2ln2:
A(t)=A0e−λt
Let me work through this step by step:
- Set up the equation for 1% activity We want A(t)=0.01A0, so:
0.01A0=A0e−λt
Dividing both sides by A0:
0.01=e−λt
- Take the natural logarithm
ln(0.01)=−λt
Since 0.01=1001=10−2:
ln(10−2)=−λt
−2ln10=−λt
2ln10=λt
- Express the decay constant in terms of half-life …
- TG EAPCET 2022Set eng-2022-07-20-FN1 markMCQQ.If the velocity of light C, the gravitational constant G and Planck’s constant h are chosen as the fundamental units, the dimension of density in the new system is (A) C3G−2h1 (B) C5G−2h−1 (C) C−3/2G−1/2h1/2 (D) C9/2G−1/2h−1/2
›Reveal solutionSolution
We treat density as a product of powers of C, G, and h, solve the system of dimensional equations, and find that density has dimensions C5G−2h−1, which corresponds to option (B).
The key idea here is dimensional analysis — a powerful tool that lets us express any physical quantity in terms of chosen fundamental units. When we pick C (velocity), G (gravitational constant), and h (Planck’s constant) as base units, we need to find how density ρ (mass per volume) relates to them. The trick is to write density as [ρ]=CaGbhc and solve for a, b, c using the known dimensions of each quantity.
Let’s recall the dimensions in the standard MLT (mass, length, time) system:
- Velocity C: [C]=LT−1
- Gravitational constant G: from Newton’s law F=Gr2m1m2, we get [G]=M−1L3T−2
- Planck’s constant h: from E=hν, we have [h]=ML2T−1
- Density ρ: [ρ]=ML−3
Now we set up the equation:
- Write the dimensional equation We assume [ρ]=[C]a[G]b[h]c. Substituting dimensions:
M1L−3T0=(LT−1)a⋅(M−1L3T−2)b⋅(ML2T−1)c
- Expand and collect powers Right side becomes:
M−b+c⋅La+3b+2c⋅T−a−2b−c
-
Equate exponents for M, L, T
For mass: 1=−b+c
For length: −3=a+3b+2c
For time: 0=−a−2b−c
-
Solve the system
From the mass equation: c=1+b
From the time equation: a=−2b−c=−2b−(1+b)=−3b−1
Substitute into the length equation:
−3=(−3b−1)+3b+2(1+b)
Simplify: −3=−3b−1+3b+2+2b …
- KCET 2019Set A-11 markMCQQ.In Rutherford experiment, for head-on collision of α-particles with a gold nucleus, the impact parameter is (A) zero (B) of the order of 10−14 m (C) of the order of 10−10 m (D) of the order of 10−6 m
›Reveal solutionSolution
In a head-on collision, the α-particle is aimed directly at the nucleus, so the perpendicular distance between the initial velocity line and the nucleus — the impact parameter — is exactly zero.
The key idea here is the definition of impact parameter in Rutherford's scattering experiment. The impact parameter b is the perpendicular distance between the initial velocity vector of the α-particle and the centre of the target nucleus. It tells you how "off-centre" the collision is.
For a head-on collision, the α-particle is aimed straight at the nucleus. That means the line of the initial velocity passes directly through the centre of the nucleus. The perpendicular distance from that line to the centre is therefore zero.
-
Recall the definition: Impact parameter b = distance of closest approach if the nucleus were not there — it's the miss distance. Mathematically, if the initial velocity is along a line, b is the perpendicular distance from the nucleus centre to that line.
-
Head-on means zero miss distance: When the α-particle is fired straight at the nucleus, there is no "miss" — it's coming right at it. So b=0.
-
Consequences: For b=0, the α-particle experiences the maximum repulsive force (Coulomb force) and comes to rest momentarily at the distance of closest approach before being repelled back. This is the case that gives the largest scattering angle (180∘). …
-
🎓Unlock everything free for 14 days
- ✓Full step-by-step solutions
- ✓Concept-first explanations
- ✓Methods, shortcuts & mistakes
- ✓PYQ mapping + timed mock tests
Full access for 14 days. No credit card required.