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NCERT Exemplar · Q8

Q.Colligative properties depend on ____________.

(i) the nature of the solute particles dissolved in solution.
(ii) the number of solute particles in solution.
(iii) the physical properties of the solute particles dissolved in solution.
(iv) the nature of solvent particles.
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Colligative properties are characteristics of solutions that depend solely on the concentration (number of particles) of the solute, not on its chemical identity. The correct option is (ii).

Colligative properties (boiling-point elevation, freezing-point depression, osmotic pressure, relative lowering of vapour pressure) are all directly proportional to the concentration, or number, of solute particles in solution - not their chemical nature.

For electrolytes like NaCl, one mole of solute dissociates into multiple ions (e.g. Na+ and Cl-), so 1 mole of NaCl produces 2 moles of particles, giving roughly twice the colligative effect of 1 mole of a non-electrolyte like glucose.

Evaluating the options:

  • (i) the nature of the solute particles - incorrect; chemical identity does not directly determine the colligative effect.
  • (ii) the number of solute particles in solution - correct; all colligative properties are directly proportional to particle count. …

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