Q.Express unified atomic mass unit in kg.
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🔒 Start your 14-day free trial to unlock the full solution →Concept understanding — Unit Conversion
Unit Conversion: Why 1 Metre and 100 Centimetres Are the Same Thing
Imagine you're measuring the length of your desk. You pull out a ruler marked in centimetres and find it's 120 cm long. Your friend, using a metre stick, says it's 1.2 m. You're both right — you've just used different units to describe the same physical length.
That's the core idea: unit conversion is the process of changing how you express a quantity without changing the quantity itself.
The Intuition: Same Quantity, Different Labels
Think of a pizza. Whether you call it "one pizza" or "8 slices," the amount of pizza hasn't changed. You've just used a different unit (pizza vs. slice) to describe it.
Similarly, 1 metre and 100 centimetres are the same length — just like 1 pizza and 8 slices are the same amount. The number changes (1 becomes 100, or 1 becomes 8), but the actual thing being measured stays identical.
This is the most important idea to hold onto: conversion changes the number, not the quantity. If you ever feel like the quantity has changed, you've made a mistake.
The Precise Statement
Unit conversion is the multiplication of a quantity by a conversion factor — a fraction equal to 1 — that cancels the old unit and introduces the new one.
A conversion factor looks like this:
old unitnew unit=1
For length: 100 cm1 m=1 and 1 m100 cm=1.
Why are these fractions equal to 1? Because 1 metre is 100 centimetres. The numerator and denominator describe the same physical length, so their ratio is exactly 1.
How to Convert: The Only Rule You Need
Multiply by a conversion factor that cancels the unit you have and leaves the unit you want.
Let's convert 120 cm to metres:
- Start with what you have: 120 cm
- Choose the conversion factor that has "cm" in the denominator (to cancel it) and "m" in the numerator: 100 cm1 m
- Multiply:
120 cm×100 cm1 m=100120 m=1.2 m
The "cm" units cancel just like numbers do: cmcm=1.
Always write the units explicitly. If the units don't cancel correctly, you've used the wrong conversion factor. This catches 90% of conversion mistakes.
The Reverse: Metres to Centimetres
Now convert 1.2 m to cm. This time, you want "cm" to remain and "m" to cancel. Use 1 m100 cm:
1.2 m×1 m100 cm=1.2×100 cm=120 cm
Notice: when going from a larger unit (m) to a smaller unit (cm), the number gets larger (1.2 → 120). When going from smaller to larger, the number gets smaller (120 → 1.2). This is a useful sanity check.
Common Conversion Factors You'll Use
| Quantity | Relationship | Conversion Factors |
|---|---|---|
| Length | 1 m = 100 cm | 100 cm1 m, 1 m100 cm |
| Mass | 1 kg = 1000 g | 1000 g1 kg, 1 kg1000 g |
| Time | 1 h = 60 min | 60 min1 h, 1 h60 min |
| Speed | 1 km/h = 36001000 m/s | 1 km1000 m×3600 s1 h |
Why this formula?
Dimensional Analysis: Why the Key Principles Hold
Dimensional Analysis is a powerful tool in physics and engineering that lets us check the consistency of equations, derive relationships, and convert units. But why does it work? Let's build the reasoning from the ground up.
1. The Core Idea: Physical Quantities Have Dimensions
Every physical quantity (like length, time, mass) can be expressed in terms of fundamental dimensions. The most common set in mechanics is:
- L = Length
- M = Mass
- T = Time
For example:
- Speed has dimensions [LT−1]
- Force has dimensions [MLT−2]
- Energy has dimensions [ML2T−2]
Why this matters: Two quantities can only be meaningfully compared or equated if they have the same dimensions. You cannot add apples to oranges — and you cannot add length to time.
2. The Principle of Dimensional Homogeneity
The key formula that underpins everything is:
Every valid physical equation must be dimensionally homogeneous.
This means: the dimensions on the left-hand side must equal the dimensions on the right-hand side.
Why must this hold?
Consider an equation like:
v=u+at
- Left side: [v]=LT−1
- Right side: [u]=LT−1, [at]=(LT−2)(T)=LT−1
Both sides have dimensions LT−1. If they didn't match, the equation would be physically meaningless — you'd be comparing quantities that cannot be equal in any real experiment.
Reasoning: Physical laws describe relationships between measurable quantities. If the dimensions don't match, the equation cannot represent a real physical relationship, because the numerical value would depend on the arbitrary choice of units.
3. The Buckingham Pi Theorem: Why We Can Derive Relationships
This is the deeper mathematical reason. The Buckingham Pi Theorem states:
If a physical problem involves n variables and k fundamental dimensions, then it can be reduced to n−k independent dimensionless groups (called π groups).
Why does this work?
Imagine you have a relationship:
f(Q1,Q2,…,Qn)=0
where each Qi has dimensions. Because the equation must be dimensionally homogeneous, we can rearrange it into a function of dimensionless products only:
F(π1,π2,…,πn−k)=0
The reasoning: Dimensions act as constraints. Each fundamental dimension (M, L, T) gives one constraint. So if you have n variables and k constraints, you only have n−k independent dimensionless combinations.
Example: For a simple pendulum, the period T depends on length L, mass m, and gravity g. That's 4 variables with 3 dimensions (M, L, T). So 4−3=1 dimensionless group: π=LT2g. This tells us T∝L/g without solving any differential equation.
4. Why We Can Convert Units Using Dimensional Analysis
The conversion factor formula:
Value in new unit=Value in old unit×(new unitold unit)dimension exponent
Why this works: …
The unified atomic mass unit (u) is defined as exactly one-twelfth the mass of a carbon-12 atom. Carbon-12 has 6 protons and 6 neutrons, and its atomic mass is defined to be exactly 12 u.
From experimental measurements, one mole of carbon-12 atoms has a mass of exactly 12 grams. Using Avogadro's number NA=6.022×1023 mol−1, we can find the mass of a single carbon-12 atom:
Mass of one C-12 atom=6.022×102312 g=6.022×102312×10−3 kg
Since this mass equals 12 u by definition, one atomic mass unit is: …
The unified atomic mass unit is defined as exactly one-twelfth the mass of a carbon-12 atom; converting through Avogadro's number gives u=1.66054×10−27 kg.
The unified atomic mass unit (u, sometimes written as amu or dalton) is the standard unit for expressing atomic and molecular masses. It provides a convenient scale because atomic masses in u are close to their mass numbers, making calculations in chemistry and nuclear physics far more intuitive than working with kilograms directly.
The definition is precise: one unified atomic mass unit is exactly 121 of the mass of a single neutral carbon-12 atom in its ground state. This choice anchors the atomic mass scale to a stable, abundant isotope.
Converting u to kilograms
The conversion hinges on two experimentally determined constants: the molar mass of carbon-12 and Avogadro's number.
1. Start with the molar mass of carbon-12
By definition, the molar mass of 12C is exactly 12 g/mol=0.012 kg/mol. This means one mole of carbon-12 atoms has a mass of exactly 12 grams.
2. Relate molar mass to individual atomic mass
One mole contains Avogadro's number of atoms:
NA=6.02214076×1023 mol−1
Therefore, the mass of a single carbon-12 atom is:
m12C=6.02214076×10230.012 kg=1.99265×10−26 kg
3. Apply the definition of the unified atomic mass unit
Since 1u=121m12C, we have:
u=121.99265×10−26=1.66054×10−27 kg …
Concept: Unified Atomic Mass Unit (u) and its Relation to Carbon-12
The unified atomic mass unit (1u) is defined based on the mass of one atom of carbon-12 (12C).
Definition
1 u is exactly one-twelfth (121) of the mass of one atom of carbon-12.
Method: Direct Definition Method
This method uses the definition of the atomic mass unit and the known mass of one mole of carbon-12.
Steps
-
Recall the molar mass of carbon-12
One mole of 12C atoms has a mass of exactly 12 g (by definition of the mole).
-
Find the mass of one atom of carbon-12
One mole contains Avogadro’s number (NA=6.022×1023) of atoms.
So, mass of one 12C atom is:
Mass of one 12C atom=6.022×102312g
- Apply the definition of 1 u By definition:
1u=121×(mass of one 12C atom)
Substitute from step 2:
1u=121×6.022×102312g
- Simplify The 12 cancels:
1u=6.022×10231g
- Convert grams to kilograms …
Let’s break this down step by step — first the concept, then the common mistakes, and finally how to avoid each.
Concept First: What is the unified atomic mass unit?
The unified atomic mass unit (symbol: u, also called amu or Da) is defined as:
1 u = 121 of the mass of one atom of carbon-12.
The mass of one carbon-12 atom is exactly 12 u, by definition.
To express 1 u in kg, we use the known mass of a carbon-12 atom in kilograms:
- Mass of one 12C atom = 1.992647×10−26 kg (approximately)
So:
1 u=121.992647×10−26 kg
1 u≈1.660539×10−27 kg
This is the standard value used in exams (often rounded to 1.66×10−27 kg).
Common Mistakes & How to Avoid Them
✗ Mistake 1: Using Avogadro’s number incorrectly
What students do:
They write:
1 u=NA1 g
and then convert g to kg incorrectly, or forget the conversion entirely.
Why it’s wrong:
While it’s true that 1 u=NA1 g/mol, this is a derived relation, not the definition. If you use it, you must:
- Remember NA=6.022×1023 mol−1
- Convert 1 g to 10−3 kg
How to avoid:
Always start from the definition (carbon-12 mass divided by 12). If you use Avogadro’s number, write the full conversion:
1 u=6.022×1023 mol−110−3 kg/mol≈1.66×10−27 kg
✗ Mistake 2: Forgetting the factor of 12
What students do:
They take the mass of a carbon-12 atom and directly say that’s 1 u.
Why it’s wrong:
The mass of one 12C atom is 12 u, not 1 u. So dividing by 12 is essential.
How to avoid:
Memorise the definition as a formula:
1 u=12mass of one 12C atom
✗ Mistake 3: Wrong power of 10
What students do:
They write 1.66×10−26 kg or 1.66×10−28 kg.
Why it’s wrong:
The correct exponent is -27. A common slip is to misplace the decimal when dividing 1.99×10−26 by 12.
How to avoid: …
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