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Q.What are the drawbacks of Rutherford's nuclear model of the atom? State and explain the postulates of Bohr's model of the atom.
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Start your 14-day free trial to unlock the full solution →Rutherford's nuclear model failed on stability and spectra; Bohr's postulates patch exactly these two gaps.
Drawbacks of Rutherford's nuclear model:
- Instability of the atom: According to classical electromagnetic theory, an accelerating (orbiting) charge must continuously radiate energy as electromagnetic waves. An electron revolving around the nucleus is constantly accelerating (centripetal acceleration), so it should continuously lose energy, causing its orbital radius to shrink — it would spiral into the nucleus in about s. This predicts atoms are unstable, which contradicts the observed long-term stability of matter.
- Could not explain line spectra: If the electron were continuously radiating energy while spiralling inward, its frequency of revolution (and hence the emitted radiation's frequency) would change continuously, producing a CONTINUOUS spectrum. But atoms are observed to emit/absorb only certain SHARP, DISCRETE wavelengths (line spectra) — Rutherford's model gives no explanation for this.
Bohr's postulates:
- Stable, non-radiating orbits: An electron in an atom can revolve only in certain special, stable orbits (called stationary states) without radiating energy, even though it is accelerating — this postulate simply overrides the classical prediction to match observation.
- Quantisation of angular momentum: Only those orbits are allowed for which the electron's orbital angular momentum is an integral multiple of : …
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