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Q.A student was asked by his teacher to separate an impure sample of sulphur containing sand as impurity. He tried to purify it with the help of sublimation. But he was not successful; particles of sulphur could not be separated completely from sand:

(i) Why did not the sublimation process succeed?
(ii) Suggest an alternate method to affect the separation.
(iii) What is the value based information associated with it? OR What are Carbanions? How are they classified? Give their order of stability.
Jammu Kashmir JkboseJammu and Kashmir Board of School Education (Class 11) 2023Subjective· 3mImportance★★★★★
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Sublimation fails here because sulphur does not sublime cleanly on its own; the reliable alternative is dissolving the mixture in CS2 (which dissolves only sulphur), filtering off the sand, and evaporating the filtrate.

  1. Why sublimation did not succeed: Sublimation is used to separate a sublimable solid from a non-sublimable one, and works well only when the sublimable component vaporises cleanly and can be re-condensed as a pure solid, leaving the non-volatile component completely behind. In this case, sulphur does not behave as a clean, efficient subliming solid under ordinary heating conditions — on heating, it tends to melt (sulphur has a fairly low melting point) and only partially vaporise, rather than sublime completely and directly from solid to vapour. As a result, molten or partially-vaporised sulphur can remain in contact with, or re-mix with, the fine sand particles, so the separation is incomplete.
  2. Alternate method — solvent extraction: A reliable alternative is to use the difference in solubility of the two components: sulphur is readily soluble in carbon disulphide (CS2), while sand (silicon dioxide) is completely insoluble in it. Procedure:
  1. Add CS2 to the sulphur-sand mixture and stir; sulphur dissolves, sand does not.
  2. Filter the mixture — the insoluble sand is retained on the filter paper, and the sulphur passes through, dissolved in the CS2, as the filtrate.
  3. Evaporate the CS2 from the filtrate (carefully, as CS2 is volatile and flammable) to obtain pure solid sulphur.

(iii) Value-based information:

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