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Chemistry · Ch 3 — Thermodynamics

Spontaneity

3.6

Spontaneity

Knowing ΔH\Delta H is not enough to predict whether a reaction happens on its own. This part builds the real criterion for spontaneity — entropy, and then Gibbs energy, which combines enthalpy and entropy into a single sign test:

  • Is Decrease in Enthalpy a Criterion for Spontaneity? — why ΔH<0\Delta H < 0 alone isn't enough.
  • Entropy and Spontaneity — disorder as the real driving force.
  • Gibbs Energy and Spontaneity — combining ΔH\Delta H and ΔS\Delta S into ΔG\Delta G.
  • Entropy and Second Law of Thermodynamics — the total entropy of system + surroundings. …