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Q.Rutherford atom model is based on the classical concept that electrons are revolving around a central positive nucleus.
(a) Mention the drawback of Rutherford atom model and how it is rectified in Bohr's atom model?
(b) From Bohr's theory obtain the de Broglie wavelength of an electron orbiting around the nucleus.
(c) Give the statement of Heisenberg's uncertainty principle and express it mathematically. (Scores : 1+2+2)
Kerala DhseKerala DHSE Plus Two Board 2013Subjective· 5mImportance★★★★★
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Start your 14-day free trial to unlock the full solution →Rutherford's classical planetary atom is unstable and gives no line spectrum; Bohr fixed both flaws by quantising angular momentum, which — combined with de Broglie's hypothesis — shows an electron orbit is a standing wave (2πr = nλ); Heisenberg's principle sets a fundamental limit, Δx·Δp ≥ h/4π, on knowing position and momentum together.
- Drawback of Rutherford's model and Bohr's fix In Rutherford's model, electrons revolve around the nucleus under Coulomb attraction, exactly like planets around the sun. But classical electromagnetic theory says an accelerating (centripetally accelerating, i.e. revolving) charge must continuously radiate electromagnetic energy. As the electron loses energy this way, it would spiral inward and crash into the nucleus in a fraction of a second — meaning atoms would be unstable, and since the radiated frequency would change continuously as the radius shrank, the model also predicts a continuous spectrum, not the sharp lines actually observed. Bohr rectified this by postulating that electrons move only in certain special, non-radiating stationary orbits, for which the angular momentum is quantised: , . As long as the electron stays in such an orbit it does not radiate, so the atom is stable; radiation is emitted or absorbed only when the electron jumps between two such orbits, and the discreteness of the allowed orbits explains the discrete (line) spectrum.
- De Broglie wavelength from Bohr's theory Bohr's quantisation condition is: De Broglie's hypothesis gives the wavelength associated with the orbiting electron as . Substituting: …
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