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Q.Arrive at the quantum condition proposed in second postulate of Bohr's atom model using de Broglie's equation.

Kerala DhseKerala DHSE Plus Two Board 2026Subjective· 2mImportance★★★★★
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De Broglie's matter-wave hypothesis, applied by requiring a whole number of electron wavelengths to fit exactly around a stable orbit, reproduces Bohr's postulate that angular momentum is quantized in units of h/2πh/2\pi.

Bohr's second postulate states that an electron can revolve only in those orbits for which its angular momentum is an integral multiple of h/2πh/2\pi:

L=mvr=nh2π,n=1,2,3,…L = mvr = \frac{nh}{2\pi},\qquad n = 1,2,3,\dots

De Broglie later gave a physical justification for this using the wave nature of matter. According to de Broglie, a particle of momentum p=mvp = mv has an associated wavelength

λ=hmv\lambda = \frac{h}{mv}

For an electron orbit to be stable (a stationary state, not radiating energy), de Broglie argued that the electron's wave must form a standing wave around the circular orbit — it must close on itself smoothly after one revolution, which requires the orbit's circumference to be an exact whole number of wavelengths:

2πr=nλ,n=1,2,3,…2\pi r = n\lambda,\qquad n = 1,2,3,\dots …

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