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Chemistry · Ch 10 — States of Matter

Derivation of Ideal Gas Equation

10.5.1

Derivation of Ideal Gas Equation

The ideal gas equation is obtained by combining the three proportionalities of Boyle's, Charles's and Avogadro's laws. At constant TT and nn, V∝1/PV \propto 1/P (Boyle's law); at constant PP and nn, V∝TV \propto T (Charles's law); at constant PP and TT, V∝nV \propto n (Avogadro's law). Combining all three simultaneously gives V∝nTPV \propto \frac{nT}{P}, and introducing a single proportionality constant RR turns this into V=RnTPV = \frac{RnT}{P}, which rearranges to PV=nRTPV = nRT -- the ideal gas equation, also called the equation of state for an ideal gas because, given any three of the four variables PP, VV, nn, TT, the fourth can always be calculated from it. RR is called the gas constant, and becau …