Chemistry · Ch 4 — Chemical Thermodynamics
Entropy and spontaneity (Second law of Thermodynamics)
4.11.3
Entropy and spontaneity (Second law of Thermodynamics)
Look at the following examples:
i. The entropy increases when ice melts above 0 °C and when water vaporizes at 100 °C. Both are spontaneous.
ii. Consider the spontaneous reaction at room temperature:
The entropy increases due to the formation of O gas.
From the above examples, it is clear that the entropy of the system increases in the spontaneous processes. But consider the reaction
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