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Chemistry · Ch 4 — Chemical Thermodynamics

Standard enthalpy of reaction (ΔrH0)

4.10.3

Standard enthalpy of reaction (ΔrH0)

To compare the enthalpy changes of different reactions, they have to be reported under a similar set of conditions.

Thermodynamic standard state : The standard state of a substance is the form in which the substance is most stable at a pressure of 1 bar and at temperature 298 K. If the reaction involves species in solution, its standard state refers to 1 M concentration.

Standard states of certain elements and compounds are H2_2(g), Hg(ll), Na(s) or C(graphite), C2_2H5_5OH(ll), H2_2O(ll), CaCO3_3(s) and CO2_2(g) — each referring to 1 bar and 25 0^0C. …