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Exercises · 11.33

Q.An aqueous solution of borax is

(a) neutral
(b) amphoteric
(c) basic
(d) acidic
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Borax hydrolyses to give a strong base and a weak acid, so the correct option is (c) basic.

  1. Composition of borax. Borax, Na2B4O7⋅10H2O\text{Na}_2\text{B}_4\text{O}_7\cdot 10\text{H}_2\text{O}, can be thought of as the salt formed from sodium hydroxide (a strong base) and boric acid (a weak, monobasic acid).
  2. Hydrolysis in water. When dissolved in water, borax hydrolyses:

Na2B4O7+7H2O→2NaOH+4H3BO3\text{Na}_2\text{B}_4\text{O}_7 + 7\text{H}_2\text{O} \rightarrow 2\text{NaOH} + 4\text{H}_3\text{BO}_3

  1. Why the solution is basic. Since the base produced (NaOH) is strong and fully dissociates, while the acid produced (H3_3BO3_3) is weak and only partially ionises, the solution contains an excess of free hydroxide ions relative to the acid's ionisation, making the overall solution alkaline (basic) to litmus. …

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