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Physics · Ch 10 — Thermal Properties of Matter

Summary

Summary

  • Temperature is the measure of hotness; heat is energy in transit due to a temperature difference.
  • The Celsius, Fahrenheit, and Kelvin scales are related by: TC=TK−273.15T_C = T_K - 273.15 and TC100=TF−32180\frac{T_C}{100} = \frac{T_F - 32}{180}.
  • Thermal expansion: linear ΔL=L0αΔT\Delta L = L_0 \alpha \Delta T, areal ΔA=A0βΔT\Delta A = A_0 \beta \Delta T with β=2α\beta = 2\alpha, and volumetric ΔV=V0γΔT\Delta V = V_0 \gamma \Delta T with γ=3α\gamma = 3\alpha.
  • Specific heat capacity: Q=mcΔTQ = m c \Delta T; molar specific heat C=McC = M c.
  • Latent heat: Q=mLQ = m L (no temperature change during phase change).
  • Calorimetry: heat lost by hot body = heat gained by cold body (in an isolated system).
  • Heat transfer modes: conduction (Fourier's law Qt=kAT1−T2d\frac{Q}{t} = k A \frac{T_1 - T_2}{d}), convection (fluid motion), and radiation (Stefan-Boltzmann law P=σAeT4P = \sigma A e T^4).
  • Newton's law of cooling: rate of cooling ∝\propto temperature difference with surroundings; dTdt=−k(T−T0)\frac{dT}{dt} = -k (T - T_0).
  • Thermal conductivity kk: good conductors have high kk; insulators have low kk.
  • Ideal gas equation: PV=nRTPV = nRT; absolute zero is −273.15∘-273.15^\circC.

Quick Reference: Key Quantities, Symbols, Dimensions and Units

QuantitySymbolDimensionsUnitRemark
Amount of substanceμ\mudimensionlessmol—
Celsius temperaturetCt_C[K][K]°CtC=T−273.15t_C = T - 273.15
Kelvin absolute temperatureTT[K][K]K—
Coefficient of linear expansionαl\alpha_l[K−1][K^{-1}]K−1K^{-1}—