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Q.Describe the characteristics of photoelectric effect. Establish Einstein's photoelectric equation and show how it explains the characteristics. (3+4=7)

Odisha ChseOdisha CHSE +2 Science Board Exam 2023Subjective· 7mImportance★★★★★
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Photoelectric emission shows a threshold frequency, an instantaneous response, and a maximum kinetic energy that depends on frequency (not intensity) — all explained by Einstein's photon-based equation KEₘₐₓ = hν − φ₀.

Characteristics of the photoelectric effect (from experiment):

  1. Threshold frequency: For a given metal, photoelectric emission occurs only if the frequency of incident light is above a certain minimum value ν0\nu_0 (the threshold frequency); below it, no electrons are emitted, however intense the light.
  2. Instantaneous emission: Photoelectrons are emitted almost instantaneously (within 10−910^{-9} s) as soon as light of suitable frequency falls on the metal — there is no measurable time lag, even for very low intensity.
  3. Effect of intensity: For a fixed frequency (above threshold), the photoelectric current (i.e. the number of photoelectrons emitted per second) is directly proportional to the intensity of incident light, but the maximum kinetic energy of the emitted electrons does NOT depend on intensity at all.
  4. Effect of frequency: The maximum kinetic energy of the photoelectrons increases linearly with the frequency of the incident light (above threshold), independent of the intensity.

Einstein's photoelectric equation: Einstein proposed that light consists of discrete packets (photons), each of energy hνh\nu. When a photon strikes an electron in the metal, it is absorbed completely (one photon → one electron), giving up all its energy hνh\nu instantly. Part of this energy, equal to the work function ϕ0\phi_0, is used to free the electron from the metal surface, and the rest appears as the kinetic energy of the emitted electron:

hν=ϕ0+KEmaxh\nu = \phi_0 + KE_{max}

KEmax=hν−ϕ0=h(ν−ν0)KE_{max} = h\nu - \phi_0 = h(\nu -\nu_0), since ϕ0=hν0\phi_0 = h\nu_0

In terms of the stopping potential V0V_0 (since eV0=KEmaxeV_0 = KE_{max}):

eV0=hν−ϕ0eV_0 = h\nu - \phi_0

How this explains the characteristics:

  • Threshold frequency: If ν<ν0\nu <\nu_0, then hν<ϕ0h\nu < \phi_0, making KEmaxKE_{max} negative, which is unphysical — so no emission is possible below ν0\nu_0. This directly explains the existence of a threshold frequency, ν0=ϕ0/h\nu_0 = \phi_0/h. …

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