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Choose the Best Answer · Q14

Q.Assertion: In mono haloarenes, electrophilic substitution occurs at ortho and para positions. Reason: Halogen atom is a ring deactivator.

(i) If both assertion and reason are true and reason is the correct explanation of assertion.
(ii) If both assertion and reason are true but reason is not the correct explanation of assertion.
(iii) If assertion is true but reason is false.
(iv) If both assertion and reason are false.
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Step 1. Assertion: in monohaloarenes, electrophilic substitution occurs at ortho and para positions -- true, since the halogen's lone-pair resonance donation raises electron density specifically at those positions.

Step 2. Reason: the halogen atom is a ring deactivator -- also true, since the halogen's -I inductive effect withdraws electron density overall, making the ring less reactive than plain benzene.

Step 3. However, deactivation (the reason given) is NOT what causes ortho/para direction (the assertion). Deactivation is caused by the inductive (-I) effect; ortho/para direction is caused by the SEPARATE resonance (+M) effect of the halogen's lone pair. A substituent can in principle be a deactivator and still be a meta director (like -NO2) -- it just happens that halogen's resonance donation specifically favour …

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