Q.Assertion: In mono haloarenes, electrophilic substitution occurs at ortho and para positions. Reason: Halogen atom is a ring deactivator.
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Start your 14-day free trial to unlock the full solution →Step 1. Assertion: in monohaloarenes, electrophilic substitution occurs at ortho and para positions -- true, since the halogen's lone-pair resonance donation raises electron density specifically at those positions.
Step 2. Reason: the halogen atom is a ring deactivator -- also true, since the halogen's -I inductive effect withdraws electron density overall, making the ring less reactive than plain benzene.
Step 3. However, deactivation (the reason given) is NOT what causes ortho/para direction (the assertion). Deactivation is caused by the inductive (-I) effect; ortho/para direction is caused by the SEPARATE resonance (+M) effect of the halogen's lone pair. A substituent can in principle be a deactivator and still be a meta director (like -NO2) -- it just happens that halogen's resonance donation specifically favour …
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