Q.Compare SN1 and SN2 reaction mechanisms.
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Start your 14-day free trial to unlock the full solution →Step 1. Kinetics. SN2's rate depends on BOTH the alkyl halide and the nucleophile's concentration (second order overall, Rate = k2[RX][Nu-]); SN1's rate depends ONLY on the alkyl halide's concentration (first order overall, Rate = k[RX]), since the nucleophile plays no part in the slow step.
Step 2. Number of steps. SN2 is a single, concerted step -- nucleophile attack and halide departure happen together, with one transition state and no discrete intermediate. SN1 is two steps -- a slow ionisation to a carbocation, then a fast nucleophilic attack on that cation.
Step 3. Stereochemistry. SN2 proceeds by backside attack (the nucleophile approaches opposite the leaving group), inverting the configuration at the reacting carbon (Walden inversion) -- a single, defined stereochemical outcome. SN1 proceeds through a planar, sp2 carbocation that can be attacked from either face with roughly equal probability, so a chiral substrate gives a racemic (optically inactive) mixture. …
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