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Choose the Best Answer · Q11

Q.CH3Br, treated with

(i) KCN, gives (A); A, treated with
(ii) H3O+, gives (B); B, treated with
(iii) PCl5, gives (C). Product (C) is a) acetyl chloride b) chloroacetic acid c) alpha-chlorocyanoethanoic acid d) none of these
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Step 1. CH3Br + KCN (i) undergoes nucleophilic substitution (Unit 11 chemistry) to give A = methyl cyanide (acetonitrile), CH3-C#N, + KBr.

Step 2. A (methyl cyanide) + H3O+ (ii) undergoes acid hydrolysis of the nitrile (Section 12.10.2) to give B = acetic acid, CH3-COOH, + NH4+ (as ammonium ion/salt). …

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