Skip to content
Question 59 of 70

Q.(a)

(i) Mention the dispersed phase and dispersion medium present in the following colloids.
(A) Paint (B) Froths of air
(ii) Write short notes on Catalytic poison. Give example. OR
(b)
(i) What is a buffer solution ?
(ii) The KaK_a of propionic acid is 1.84×10−51.84\times10^{-5}. What is the pH of a solution containing 0.5 M propionic acid and 0.5 M sodium propionate ?
Puducherry TnboardTamil Nadu HSC (DGE) Board 2019Subjective· 5mImportance★★★★★
84% · 59/70 Questions
🔒 Locked · start free trial →

You're viewing a preview — the full solution, concept, methods & PYQ mapping are locked.

Start your 14-day free trial to unlock the full solution →

(a) Paint is a solid-dispersed-in-liquid sol, froth of air is a gas-dispersed-in-liquid foam, and a catalytic poison (e.g. arsenic) deactivates a catalyst by blocking its active sites. (b) A buffer resists pH change, and for this equal-concentration propionic-acid/propionate buffer pH=pKa≈4.74pH=pK_a\approx4.74.

(a)(i) Dispersed phase and dispersion medium:

ColloidDispersed phaseDispersion mediumType
(A) PaintSolid (pigment particles)Liquid (oil/solvent vehicle)Sol
(B) Froth of airGas (air bubbles)LiquidFoam

(a)(ii) Catalytic poison: A catalytic poison is a substance which, even in a small amount, gets preferentially adsorbed on the active sites of a (usually solid/heterogeneous) catalyst, blocking those sites and thereby reducing or completely destroying the catalyst's activity. Example: in the Contact process for manufacturing sulfuric acid, traces of arsenic compounds (e.g. As2O3As_2O_3) present in the sulfur dioxide feed gas act as a catalytic poison for the platinum catalyst used to oxidise SO2SO_2 to SO3SO_3, permanently deactivating it (which is why platinum has largely been replaced by the less easily poisoned vanadium pentoxide, V2O5V_2O_5, catalyst in modern plants). Another classic example is carbon monoxide poisoning the iron catalyst used in the Haber process for ammonia synthesis.


(b)(i) Buffer solution: A buffer solution is one that resists a (large) change in its pH when a small amount of a strong acid or strong base is added to it, or on moderate dilution. An acidic buffer is made from a weak acid together with a salt of that weak acid with a strong base (e.g. CH3COOH+CH3COONaCH_3COOH + CH_3COONa, or here propionic acid + sodium propionate), while a basic buffer is made from a weak base together with a salt of that weak base with a strong acid (e.g. NH4OH+NH4ClNH_4OH + NH_4Cl).

(b)(ii) pH of the propionic acid/sodium propionate buffer:

…

Unlock everything free for 14 days

  • Full step-by-step solutions
  • Concept-first explanations
  • Methods, shortcuts & mistakes
  • PYQ mapping + timed mock tests

Full access for 14 days. No credit card required.