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Question 47 of 61

Q.The metal extracted by Hall-Heroult process is :

(a) Cu
(b) Al
(c) Zn
(d) Ni
Puducherry TnboardTamil Nadu HSC (DGE) Board 2023MCQ· 1mImportance★★★★★
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The Hall-Heroult process electrolyses alumina dissolved in molten cryolite to deposit molten aluminium metal at the cathode.

In the Hall-Heroult process, purified alumina (Al2O3Al_2O_3, obtained from bauxite via the Bayer process) is dissolved in molten cryolite (Na3AlF6Na_3AlF_6) along with a little fluorspar (CaF2CaF_2) to lower the melting point and increase conductivity. On electrolysis in a carbon-lined steel cell (acting as cathode) with carbon anodes, Al3+Al^{3+} ions are reduced and molten aluminium metal collects at the bottom (cathode), while oxygen liberated at the anode burns away the carbon anodes as CO2CO_2. Cu is extracted by electrolytic refining/smelting of copper ores, Zn mainl …

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