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Question 45 of 69

Q.The IUPAC name of dimethyl sec. butylamine is :

(a) 2-amino-3-methyl butane
(b) 2-(N-methyl amino) butane
(c) 2-(N, N-dimethyl amino) butane
(d) 2-(N, N-dimethyl amino) propane
Puducherry TnboardTamil Nadu HSC (DGE) Board 2017MCQ· 1mImportance★★★★★
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The compound is a tertiary amine with a sec-butyl group and two methyl groups on nitrogen; IUPAC substitutive nomenclature names it as 2-(N,N-dimethylamino)butane.

sec-Butyl is CH3CH2CH(CH3)−CH_3CH_2CH(CH_3)-, attached through its C-2. In 'dimethyl sec-butylamine', both methyl groups and the sec-butyl group are on the same nitrogen: (CH3)2N−CH(CH3)CH2CH3(CH_3)_2N-CH(CH_3)CH_2CH_3. Treating the four-carbon chain (butane) as the parent and the −N(CH3)2-N(CH_3)_2 group as an (N,N-dimethylamino) substituent at C-2 gives the IUPAC name 2-(N,N-dimethylamino)butane. Option (a) describes a diamine-type name for a differen …

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