Why Photon Energy is E=hf — The Reasoning Behind the Formula
The formula E=hf is not something you memorise and plug numbers into. It comes from a deep shift in how physicists understood light.
The problem that forced the formula
By the late 1800s, classical physics said light was a wave — continuous, carrying energy in proportion to its intensity (brightness). But blackbody radiation and the photoelectric effect showed something bizarre: when you shine light on a metal, electrons are ejected only if the light's frequency is above a certain threshold, no matter how bright the light is. Below that frequency, even the brightest lamp won't kick out a single electron. Classically this made no sense — a wave's energy depends on amplitude, not frequency.
Einstein's radical idea (1905)
Einstein proposed that light comes in discrete packets — photons — each carrying a fixed energy that depends only on its frequency, with Planck's constant h as the proportionality:
A single photon's energy is E=hf, where f is the frequency of the light.
This directly explains the photoelectric effect: an electron needs a minimum energy (the work function ϕ) to escape. If a photon's energy hf<ϕ, no electron is ejected — regardless of how many photons you send, because each photon interacts with one electron individually.
E=hf is not derived from deeper principles — it is a postulate justified by the experiments it explains, and it unified optics with quantum mechanics.
The equivalent forms
Since c=fλ for light in vacuum, the same idea in terms of wavelength is:
E=λhc
Use this when you're given λ instead of f. A photon also carries momentum (despite having no mass): …