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Exercises · 11.3

Q.Explain why

(a) Two bodies at different temperatures T1T_1 and T2T_2 if brought in thermal contact do not necessarily settle to the mean temperature (T1+T2)/2(T_1 + T_2)/2.
(b) The coolant in a chemical or a nuclear plant (i.e., the liquid used to prevent the different parts of a plant from getting too hot) should have high specific heat.
(c) Air pressure in a car tyre increases during driving.
(d) The climate of a harbour town is more temperate than that of a town in a desert at the same latitude.
Sikkim CbseNCERTSubjective· 5mImportance★★★★★est
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The key idea is that thermal equilibrium depends on heat capacities, not just temperatures; high specific heat stabilises temperature; friction heats the tyre air; and water’s high specific heat moderates coastal climates.

  1. Because heat flow depends on heat capacities.
  2. High specific heat absorbs more heat per degree rise.
  3. Friction and deformation heat the air.
  4. Water’s high specific heat buffers temperature swings.

(a) Two bodies at different temperatures T1T_1 and T2T_2 if brought in thermal contact do not necessarily settle to the mean temperature (T1+T2)/2(T_1 + T_2)/2.

Concept & Intuition

When two bodies at different temperatures are placed in thermal contact, heat flows from the hotter to the colder until they reach a common final temperature. But the final temperature is not simply the arithmetic mean of the initial temperatures. Why? Because the amount of heat each body can store per degree temperature change — its heat capacity — determines how much its temperature shifts. A body with a large heat capacity changes temperature very little for a given heat transfer, while one with a small heat capacity changes a lot.

Step-by-step reasoning

  1. Heat lost = heat gained Let the two bodies have masses m1m_1, m2m_2 and specific heats c1c_1, c2c_2. Their heat capacities are C1=m1c1C_1 = m_1 c_1 and C2=m2c2C_2 = m_2 c_2. If the final equilibrium temperature is TfT_f, then:

m1c1(T1−Tf)=m2c2(Tf−T2)m_1 c_1 (T_1 - T_f) = m_2 c_2 (T_f - T_2)

assuming T1>T2T_1 > T_2.

  1. Solve for TfT_f Rearranging:

Tf=m1c1T1+m2c2T2m1c1+m2c2T_f = \frac{m_1 c_1 T_1 + m_2 c_2 T_2}{m_1 c_1 + m_2 c_2}

This is a weighted average of T1T_1 and T2T_2, with weights equal to the heat capacities.

  1. When does TfT_f equal the mean? The mean (T1+T2)/2(T_1 + T_2)/2 occurs only when m1c1=m2c2m_1 c_1 = m_2 c_2 — i.e., when the heat capacities are equal. In general, the body with the larger heat capacity dominates the final temperature. For example, if one body is a huge block of iron and the other is a tiny drop of water, the final temperature will be very close to the iron’s temperature, not the average.
Watch out

A common mistake is to assume that the final temperature is always the average. This would only be true if both bodies had identical heat capacities — which is rarely the case.


(b) The coolant in a chemical or a nuclear plant should have high specific heat.

Concept & Intuition

A coolant’s job is to absorb heat from hot parts (like reactor cores or chemical reactors) without itself rising too much in temperature. If the coolant’s temperature rises too fast, it can’t carry away enough heat, and the plant may overheat. The property that determines how much heat a substance can absorb per unit temperature rise is its specific heat capacity.

Step-by-step reasoning

  1. Heat absorbed by coolant For a mass mm of coolant with specific heat cc, the heat absorbed for a temperature rise ΔT\Delta T is:

Q=mcΔTQ = m c \Delta T

  1. Why high cc helps

    For a given QQ (the heat that must be removed), a higher cc means a smaller ΔT\Delta T. So the coolant stays cooler, maintaining a larger temperature difference with the hot parts, which drives more efficient heat transfer. Also, a smaller ΔT\Delta T reduces thermal stress on pipes and components.

  2. Practical benefit

    A high-specific-heat coolant (like water, c≈4200 J/kg⋅Kc \approx 4200 \, \text{J/kg·K}) can carry away large amounts of heat without needing a huge flow rate. This makes the cooling system more compact and safer.

Tip

Water is the most common coolant precisely because it has one of the highest specific heats of any common liquid. Liquid sodium is used in some nuclear reactors because it has a high specific heat and a high boiling point, allowing operation at higher temperatures.


(c) Air pressure in a car tyre increases during driving.

Concept & Intuition

When you drive, the tyres flex repeatedly as they roll. This flexing causes internal friction in the rubber and also friction between the tyre and the road. Friction generates heat, which warms the tyre and the air inside. According to the ideal gas law, if the volume of the tyre doesn’t change much, raising the temperature increases the pressure.

Step-by-step reasoning

  1. Source of heat

    The tyre deforms as it rotates — the part in contact with the road flattens, then springs back. This repeated deformation dissipates mechanical energy as heat (hysteresis in the rubber). Also, friction with the road surface adds heat.

  2. Effect on the air inside

    The tyre is nearly rigid (volume change is small). The air inside behaves approximately as an ideal gas. For a fixed volume VV and number of moles nn, the ideal gas law is:

PV=nRTP V = n R T

So pressure PP is directly proportional to absolute temperature TT.

  1. Temperature rise → pressure rise As the air heats up from the tyre’s heat, TT increases, so PP increases. This is why tyre pressure is higher after a long drive than when the car was cold.
Watch out

Never release air from a hot tyre to “correct” the pressure to the cold specification. The pressure will drop when the tyre cools, and you’ll end up with an underinflated tyre, which is dangerous. Always check tyre pressure when the tyres are cold.


(d) The climate of a harbour town is more temperate than that of a town in a desert at the same latitude.

Concept & Intuition

“Temperate” here means moderate — not too hot in summer, not too cold in winter. The key difference is the presence of a large body of water (the sea) near the harbour town. Water has a very high specific heat compared to land (sand, rock). This means water heats up and cools down much more slowly than land.

Step-by-step reasoning

  1. Specific heat comparison

    Water’s specific heat is about 4200 J/kg⋅K4200 \, \text{J/kg·K}, while dry sand is about 800 J/kg⋅K800 \, \text{J/kg·K}. So for the same amount of solar energy, land temperature rises about 5 times faster than water.

  2. Day/night and seasonal effects

    During the day, the land heats up quickly, making the desert town very hot. The sea stays relatively cool. At night, the land cools quickly, while the sea releases stored heat slowly. This moderates the harbour town’s temperature — the sea acts as a thermal buffer.

  3. Sea breezes

    The temperature difference between land and sea drives local winds (sea breezes during the day, land breezes at night), which further moderate the coastal climate by bringing cooler air from the sea in the afternoon.

  4. Result

    The harbour town experiences smaller daily and seasonal temperature swings (a “temperate” climate), while the desert town has extreme highs and lows.

The thermal inertia of a substance is proportional to its specific heat cc and density ρ\rho:

Thermal inertia=kρc\text{Thermal inertia} = \sqrt{k \rho c}

where kk is thermal conductivity. Water’s high ρc\rho c gives it enormous thermal inertia, smoothing out temperature fluctuations.


✓Final answer

  1. The final temperature is a heat-capacity-weighted average, not the arithmetic mean.
  2. High specific heat allows the coolant to absorb more heat per unit temperature rise, keeping the plant cooler.
  3. Friction and deformation heat the tyre air, increasing its pressure via P∝TP \propto T at constant volume.
  4. Water’s high specific heat buffers temperature changes, making coastal climates more moderate than desert climates at the same latitude.

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