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Chemistry · Ch 14 — Haloalkanes and Haloarenes

Poly Halogen Compounds

14.6

Poly Halogen Compounds

Carbon compounds carrying more than one halogen atom are poly halogen compounds. Two important dihalide classes are distinguished by WHERE the two halogens sit: (a) gem-dihalides carry both halogens on the SAME carbon, e.g. CH3-CHCl2 (ethylidene chloride, 1,1-dichloroethane) and CH3-CCl(CH3)-Cl -- i.e. (CH3)2CCl2 -- (isopropylidene chloride, 2,2-dichloropropane); (b) vic-dihalides carry the two halogens on ADJACENT carbons, e.g. ClCH2-CH2Cl (ethylene dichloride, 1,2-dichlor …