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Choose the Best Answer · Q9

Q.The compound that will react most readily with gaseous bromine has the formula (NEET)

(a) C3H6
(b) C2H2
(c) C4H10
(d) C2H4
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Step 1. C4H10 (an alkane, butane) does not react 'readily' with bromine at all under normal conditions -- it needs UV light or heat to initiate a slow free-radical substitution, so it is ruled out first.

Step 2. C2H2 (ethyne, an alkyne) does add bromine, but its sp-hybridised, more electronegative carbons hold the pi electrons more tightly than an alkene's do, making the alkyne pi system a comparatively weaker nucleophile toward Br2's electrophilic attack -- alkynes generally react more sluggishly with Br2 than alkenes do. …

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