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Question 61 of 83

Q.Cold dilute alkaline KMnO4 is known as:

(a) Schiff's reagent
(b) Fenton's reagent
(c) Tollen's reagent
(d) Baeyer's reagent
Tamil Nadu DgeTamil Nadu HSC First Year (DGE) Board 2020MCQ· 1mImportance★★★★★
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Cold, dilute, alkaline KMnO4 is called Baeyer's reagent, used in the Baeyer's test for unsaturation.

Baeyer's reagent is a cold, dilute, and alkaline (e.g. sodium-carbonate-buffered) solution of potassium permanganate. When it is added to an alkene or alkyne, the purple colour of the permanganate is decolourised as the C=C or C-C triple bond is oxidised (via a cyclic diester intermediate) to a vicinal diol, and a brown precipitate of manganese dioxide forms. This decolourisation is used as a simple qualitative test (Baeyer's test) to detect unsaturation in an organic compound.

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