Question 62 of 80
Q.Identify to which type does the following complex reactions belongs to :
(i) dehydration of 2-methyl-2-butanol
(ii) isomerisation of cyclopropane
(iii) saponification of a diester in presence of an alkali
Tamil Nadu DgeTamil Nadu HSC (DGE) Board 2018Subjective· 3mImportance★★★★★
78% · 62/80 Questions
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Start your 14-day free trial to unlock the full solution →Complex reactions are classified as opposing, side (parallel) or consecutive reactions based on how their elementary steps are related; each of the three examples given illustrates one distinct type.
- Dehydration of 2-methyl-2-butanol — Side (parallel) reaction Acid/alumina-catalysed E1 dehydration of 2-methyl-2-butanol can lose a proton from either of two different β-carbons, so two alkenes are formed simultaneously from the same carbocation intermediate: When a single reactant gives two (or more) different products by parallel paths with different rate constants (, , …), it is called a side reaction / parallel reaction.
- Isomerisation of cyclopropane — Opposing (reversible) reaction The forward isomerisation (ring opening to propene) and the reverse reaction both occur, and the system approaches an equilibrium concentration ratio rather than going to 100% completion — the hallmark of an opposing (reversible) first-order reaction, treated kinetically with both and .
- Saponification of a diester — Consecutive (sequential) reaction …
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