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Write Brief Answer · Q14

Q.Write Arrhenius equation and explain the terms involved.

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Concept understanding — Arrhenius Equation and Activation Energy

Arrhenius proposed k=Ae−Ea/RTk=Ae^{-E_a/RT}, where A is the frequency factor (roughly temperature-independent, linked to collision frequency), R the gas constant, EaE_a the activation energy, and T the absolute temperature -- packaging collision theory's derivation into one working formula. Taking logs, ln⁡k=ln⁡A−EaRT\ln k=\ln A-\dfrac{E_a}{RT}, matching y=mx+cy=mx+c: a plot of ln⁡k\ln k (or log⁡k\log k) against 1/T1/T is a straight line with NEGATIVE slope −Ea/R-E_a/R for a reaction genuinely obeying Arrhenius behaviour over its whole temperature range; a curved plot, or one with a positive slope, both signal deviation from this simple model. …

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