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Write Brief Answer · Q21

Q.A saturated solution, prepared by dissolving CaF2(s)CaF_2(s) in water, has [Ca2+]=3.3×10−4[Ca^{2+}] = 3.3 \times 10^{-4} M. What is the KspK_{sp} of CaF2CaF_2?

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Step 1. CaF2(s)⇌Ca2+(aq)+2F−(aq)CaF_2(s) \rightleftharpoons Ca^{2+}(aq)+2F^-(aq): given [Ca2+]=3.3×10−4[Ca^{2+}]=3.3\times10^{-4} M, so [F−]=2×3.3×10−4=6.6×10−4[F^-]=2\times3.3\times10^{-4}=6.6\times10^{-4} M.

Step 2. Ksp=[Ca2+][F−]2=(3.3×10−4)(6.6×10−4)2K_{sp}=[Ca^{2+}][F^-]^2=(3.3\times10^{-4})(6.6\times10^{-4})^2. …

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