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Question 62 of 69

Q.Identify the compounds A and B in the following sequence of reactions. CH3CH2NO2→Sn/HClA→CH3COClBCH_3CH_2NO_2 \xrightarrow{Sn/HCl} A \xrightarrow{CH_3COCl} B

Tamil Nadu DgeTamil Nadu HSC (DGE) Board 2023Subjective· 2mImportance★★★★★
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CH3CH2NO2CH_3CH_2NO_2 (nitroethane) is reduced by Sn/HClSn/HCl to ethylamine (A), which is then acylated by acetyl chloride to give N-ethylacetamide (B).

Step 1 (→\rightarrow A): Nitroethane, CH3CH2NO2CH_3CH_2NO_2, treated with tin and concentrated hydrochloric acid (Sn/HClSn/HCl, a strong acidic reducing combination) undergoes complete reduction of the nitro group to a primary amino group: CH3CH2NO2→Sn/HClCH3CH2NH2 (A, ethylamine)CH_3CH_2NO_2 \xrightarrow{Sn/HCl} CH_3CH_2NH_2\ (A,\ \text{ethylamine})

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