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Choose the Best Answer · Q18

Q.When copper is heated with conc. HNO3 it produces

(a) Cu(NO3)2, NO and NO2
(b) Cu(NO3)2 and N2O
(c) Cu(NO3)2 and NO2
(d) Cu(NO3)2 and NO
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Step 1. Write the reaction of copper with concentrated nitric acid.

Cu + 4HNO3(concentrated) -> Cu(NO3)2 + 2NO2 + 2H2O.

Step 2. Contrast with dilute nitric acid.

With dilute nitric acid instead, the overall reaction is 3Cu + 8HNO3(dilute) -> 3Cu(NO3)2 + 2NO + 4H2O — the reduction product is colourless nitric oxide (NO), not brown nitrogen dioxide, because dilute acid is a milder oxidant that is reduced only as far as the +2 state, whereas concentrated acid, being a stronger oxidant, is reduced only as far as +4 (NO2) before the reaction self-limits.

Step 3. Eliminate the distractors. …

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