Q.Why is diamond hard?
You're viewing a preview — the full solution, concept, methods & PYQ mapping are locked.
Start your 14-day free trial to unlock the full solution →Diamond's hardness comes from its structure — a giant, rigid three-dimensional network of strong covalent C–C bonds, not a molecular or layered arrangement.
Structure of diamond
In diamond, every carbon atom is sp³ hybridised. Each carbon atom uses its four sp³ hybrid orbitals to form four strong, localised covalent (sigma) bonds to four neighbouring carbon atoms arranged tetrahedrally (bond angle 109°28′, C–C bond length ≈ 154 pm). This tetrahedral bonding pattern repeats throughout the entire crystal, so the whole diamond crystal is effectively ONE single giant covalent molecule (a network/giant covalent solid) — there are no discrete, separate molecules.
Why this structure makes it hard
- Strong, directional covalent bonds: C–C sigma bonds are among the strongest single covalent bonds (bond energy ≈ 347 kJ/mol), and every atom is fully engaged in 4 such bonds — there are no weak links, no lone pairs, and no free/delocalised electrons.
- Continuous 3-D network: Because the bonding extends rigidly in all three dimensions (not just in sheets or chains), any applied mechanical stress must break a large number of strong covalent bonds simultaneously to deform or cleave the crystal, which requires very high energy.
- No slip planes: Unlike layered structures, diamond has no planes of weakly-bonded atoms that can slide over each other, so it resists scratching and deformation from any direction.
Contrast with graphite …
Unlock everything free for 14 days
- Full step-by-step solutions
- Concept-first explanations
- Methods, shortcuts & mistakes
- PYQ mapping + timed mock tests
Full access for 14 days. No credit card required.