Thermal Conduction — From Intuition to the Law
Imagine holding a metal rod. You put one end into a fire. After a few seconds, the end you're holding gets hot — even though it's nowhere near the flame. Something travelled through the rod. That something is heat, and the process is thermal conduction.
At the microscopic level, the atoms in the hot end vibrate violently. They bump into their neighbours, passing on some of that energy. Those neighbours bump into the next ones, and so on. In metals, free electrons also carry energy rapidly, which is why metals feel cold to the touch (they steal heat from your hand fast) and conduct heat so well. In non-metals, only the atomic vibrations (phonons) do the job, so conduction is slower.
The Precise Statement
Now for the formal description. When heat flows steadily through a slab of material — say a wall, a window, or a metal bar — experiments show that the rate of heat transfer depends on three things:
- The temperature difference across the material — bigger difference, faster flow.
- The cross-sectional area — a thicker rod or a larger wall lets more heat through.
- The thickness — a longer path slows the flow down.
Combine these observations into a single proportionality:
tQ∝AdT1−T2
where Q/t is the heat transferred per unit time (the heat current), A is the area, T1−T2 is the temperature difference, and d is the thickness.
The ratio (T1−T2)/d is the temperature gradient — how sharply the temperature changes with distance. The steeper the gradient, the faster heat flows.
Fourier's Law of Heat Conduction
The proportionality becomes an equation when we introduce a material-dependent constant, k, called the thermal conductivity:
tQ=kAdT1−T2
Or, in differential form for a continuous medium:
dtdQ=−kAdxdT
The minus sign is a convention: heat flows from hot to cold, so the temperature gradient dT/dx is negative in the direction of flow. The minus sign makes the heat current positive.
Thermal conductivity k is a property of the material. High k means a good conductor (copper, aluminium). Low k means an insulator (wood, air, fibreglass). Units: W m−1K−1.
What "Steady State" Means
The law above assumes steady-state conduction — the temperatures at each point in the material do not change with time. Heat flows in at one end and out at the other at the same constant rate. The rod doesn't keep getting hotter; it reaches a stable temperature profile. This is the simplest case and the one you'll meet first in exams.
A common mistake: thinking the temperature gradient is (T1−T2)/d only when the material is uniform and the flow is one-dimensional. That's correct for a slab. For a curved wall or a rod with varying cross-section, the gradient changes with position — but the same basic idea applies locally.
A Quick Example …