Q.If a proton had a radius R and the charge was uniformly distributed, calculate using Bohr theory, the ground state energy of a H-atom when
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The Intuition: Why Can't an Electron Just Sit Anywhere?
Imagine you're rolling a marble on a staircase. The marble can rest on any step — step 1, step 2, step 3 — but it can never float halfway between two steps. The staircase forces the marble into specific, fixed positions.
That's the core idea of the Bohr model. Before Bohr, physicists thought electrons orbited the nucleus like planets around the sun — they could be at any distance, any energy. But experiments showed something strange: atoms only emit or absorb light at very specific colours (wavelengths), not a continuous rainbow. That meant electrons could only have certain, fixed energies — like the steps of a staircase.
Bohr's genius was to say: an electron in an atom cannot have any arbitrary energy. It can only occupy certain "allowed" energy levels. When it jumps from one level to another, it either absorbs or emits a photon of light whose energy exactly matches the difference between those levels.
The Precise Statement
In the Bohr model of the hydrogen atom (and hydrogen-like ions with one electron), the electron moves in circular orbits around the nucleus. But only those orbits are allowed where the electron's angular momentum is an integer multiple of 2πh (where h is Planck's constant).
This quantisation condition leads to a simple formula for the energy of the electron in the n-th orbit:
En=−n213.6 eV
Here:
- n is the principal quantum number — a positive integer (n=1,2,3,…)
- En is the energy of the electron in that level (in electronvolts)
- The negative sign means the electron is bound to the nucleus — you need to add energy to free it
The lowest energy state (n=1) is called the ground state. Its energy is −13.6 eV. The higher states (n=2,3,4,…) are excited states — they have less negative (higher) energies.
As n increases, the energy levels get closer together. At n=∞, the energy becomes 0 eV — the electron is completely free from the atom (ionisation).
What This Explains
When an electron jumps from a higher level (ni) to a lower level (nf), it emits a photon of energy:
ΔE=Enf−Eni=13.6(nf21−ni21) eV
This single formula predicts all the spectral lines of hydrogen — the Lyman series (jumps to n=1), Balmer series (to n=2), Paschen series (to n=3), and so on. Each series corresponds to a different "final step" on the staircase. …
Why this formula?
Why the Bohr Model Gives Those Energy Levels
The Bohr model is a beautiful piece of physics because it takes a simple, almost desperate idea — "electrons only exist in certain orbits" — and derives the entire hydrogen spectrum from it. The key is that Bohr didn't just assume the energy levels; he forced them to be consistent with classical physics in one specific way, then broke with it in another.
The Two Non-Negotiable Pieces
First, the electron moves in a circle around the proton. That's pure classical mechanics: the Coulomb attraction provides the centripetal force.
4πε01r2e2=rmv2
This gives you a relation between speed v and radius r:
v2=4πε0mre2
Second, the total energy of the electron is the sum of its kinetic and potential energies. Potential energy for a Coulomb force is −4πε01re2 (negative because the force is attractive, and we set zero at infinity).
E=21mv2−4πε01re2
Substitute v2 from above:
E=21(4πε0re2)−4πε0re2=−214πε0re2
So far, nothing is quantised. Any radius r gives a valid classical orbit, and the energy just follows from that radius. The problem is that a classical electron in a curved path radiates energy and spirals into the nucleus — atoms should collapse. Bohr needed a rule to pick out stable orbits.
The Quantisation Condition
Bohr's revolutionary step was to postulate that the angular momentum of the electron is quantised in units of ℏ=h/2π:
mvr=nℏ,n=1,2,3,…
Why this particular rule? Bohr later said it was the simplest way to get the right answer. But there's a deeper physical motivation: if you think of the electron as a wave (de Broglie's idea, which came a decade later), the condition that a standing wave fits exactly around the circumference 2πr=nλ gives mvr=nℏ directly. So the quantisation condition is really a wave condition imposed on a particle picture.
The angular momentum quantisation is the only non-classical assumption in the Bohr model. Everything else follows from classical mechanics and electromagnetism.
Deriving the Allowed Radii and Energies
From mvr=nℏ, we get v=nℏ/(mr). Substitute this into the centripetal force equation:
4πε01r2e2=rm(mrnℏ)2=mr3n2ℏ2
Solve for r:
rn=me24πε0ℏ2n2
The constant in front is the Bohr radius a0≈0.529A˚. So the radii are rn=a0n2.
Now plug rn back into the energy expression E=−214πε0re2:
En=−214πε0e2⋅a0n21=−214πε0a0e2⋅n21
Substitute a0=me24πε0ℏ2:
En=−214πε0e2⋅4πε0ℏ2me2⋅n21=−8ε02h2me4⋅n21
En=−n213.6 eV …
For a point-charge proton the electron moves in a 1/r Coulomb potential, giving the ground state −13.6eV at the Bohr radius a0=0.53A˚.
(i) R=0.1A˚. Here R≪a0, so the electron's orbit lies entirely outside the charged sphere, where the potential is the ordinary Coulomb form. The finite size changes almost nothing:
E≈−13.6eV.
(ii) R=10A˚. Here R≫a0, so the electron orbits inside the uniformly charged proton. There the field is E(r)=4πϵ0eR3r — a linear (harmonic) restoring force. Bohr's condition mvr=ℏ with the force balance rmv2=4πϵ0e2R3r gives
r4=a0R3⇒r=(0.53×103)1/4≈4.8A˚(<R), …
If the proton is a uniformly charged sphere of radius R, then for R=0.1A˚(≪a0) the electron orbits outside it and E≈−13.6eV; for R=10A˚(≫a0) the electron orbits inside, feels a harmonic force, and E≈−1.8eV.
1. Potential of a uniformly charged sphere (total charge +e, radius R):
V(r)=⎩⎨⎧−4πϵ0e22R33R2−r2,−4πϵ0e2r1,r<Rr≥R.
Outside the sphere the field is the usual Coulomb field; inside it grows linearly with r.
2. Case (i): R=0.1A˚.
The Bohr radius is a0=0.53A˚, so R≪a0: the electron's orbit lies well outside the proton, where the potential is exactly Coulombic. The result is essentially unchanged:
E≈−13.6eV.
3. Case (ii): R=10A˚.
Now R≫a0, so the electron orbits inside the charged sphere. The inside field
E(r)=4πϵ0eR3r
produces a linear restoring force F=4πϵ0e2R3r (harmonic, like a spring).
4. Find the orbit radius from Bohr's condition.
With mvr=ℏ (ground state, n=1) and force balance
rmv2=4πϵ0e2R3r,
substitute v=ℏ/(mr):
mr3ℏ2=4πϵ0e2R3r⇒r4=me24πϵ0ℏ2R3=a0R3. …
Method: Compare R to a0 First, Then Use the Virial Theorem Inside the Sphere
Rather than blindly computing kinetic and potential energy by integration in every case, first check which regime you're in — this tells you immediately whether any calculation is even needed, and which shortcut applies if it is.
Steps
Step 1: Compare the given radius to the Bohr radius a0=0.53A˚
- If R≪a0: the electron's orbit lies entirely outside the charged sphere, where the field is ordinary 1/r2 Coulomb. No new calculation is needed — the ground-state energy is just the standard −13.6eV.
- If R≫a0: the electron orbits inside the sphere, where the field is linear in r (a Hooke's-law-type restoring force) — a genuinely different problem.
Step 2: For the inside-sphere case, recognise it as a power-law-force problem
Inside a uniformly charged sphere, F(r)∝r (like a spring). For any circular orbit under a central force F(r), the centripetal condition alone gives kinetic energy directly:
K=21mv2=21rF(r)
This is a general shortcut — you don't need to separately solve for v and square it once you know r and F(r).
Step 3: Find r from Bohr quantization, then get K in one line …
- Higher Secondary (+2 Stage) Examination 2026Set ANNUAL1 markMCQQ.The energy of an electron in the ground state of a hydrogen atom is -13.6 eV. What will be the energy of an electron in the third orbit of the same atom?(a) -1.51 eV(b) -3.40 eV(c) -4.53 eV(d) -6.80 eV
›Reveal solutionSolution
The energy of the nth Bohr orbit of hydrogen is En = -13.6/n² eV; putting n = 3 gives -1.51 eV.
For a hydrogen atom, the energy of the electron in the nth orbit is
En=n2−13.6 eV
For the third orbit, n = 3: …
- Higher Secondary (+2 Stage) Examination 2026Set ANNUAL1 markQ.A hydrogen atom is in its third excited state. What is the maximum number of spectral lines that can be emitted by this atom?
›Reveal solutionSolution
The third excited state of hydrogen is n = 4 (ground = n1, then 1st, 2nd, 3rd excited states are n = 2, 3, 4); the number of possible spectral lines from n down to 1 is n(n−1)/2 = 6.
For hydrogen, the ground state is n = 1. The 1st excited state is n = 2, the 2nd excited state is n = 3, and the 3rd excited state is n = 4. From the n = 4 state, an electron can drop to any of the lower levels via all possible transit …
- Higher Secondary (+2 Stage) Examination 2025Set ANNUAL1 markMCQQ.If the total energy of an electron in the first excited state of a hydrogen-like atom is -3.4 eV, then the kinetic energy and potential energy of the electron in that energy level are respectively —(a) -1.7 eV, -1.7 eV(b) -3.4 eV, 0 eV(c) 3.4 eV, -6.8 eV(d) -6.8 eV, 3.4 eV
›Reveal solutionSolution
For an electron bound by a Coulomb (1/r) force, PE = -2xKE and Total Energy = -KE (virial theorem), so from E = -3.4 eV we get KE = +3.4 eV and PE = -6.8 eV.
For an electron orbiting under an inverse-square (Coulomb) force, the virial theorem gives:
PE=−2×KE
Total energy: E=KE+PE=KE−2KE=−KE, so KE=−E.
…
- Higher Secondary (+2 Stage) Examination 2025Set ANNUAL1 markQ.Which series of the hydrogen spectrum lies in the visible region?
›Reveal solutionSolution
Of all the hydrogen spectral series, only the Balmer series (transitions ending at n=2) gives lines in the visible range (~400-700 nm); the others fall in the UV or IR.
The hydrogen spectrum consists of several series depending on which energy level the electron falls to: Lyman (falls to n=1, ultraviolet), Balmer (falls to n=2), and Paschen, Brackett, Pfund (fall to n=3,4,5 -- all in the infrared). Only the Balmer series's wavele …
- Higher Secondary (+2 Stage) Examination 2023Set ANNUAL1 markQ.The total energy of an electron in the first Bohr orbit of a hydrogen atom is -13.6 eV. What is the kinetic energy of this electron?
›Reveal solutionSolution
For an electron bound by the Coulomb force in a Bohr orbit, total energy = −(kinetic energy), so if total energy is −13.6 eV, kinetic energy is +13.6 eV.
For an electron revolving in a Bohr orbit under the Coulomb attraction of the nucleus, the potential energy is twice the negative of the kinetic energy (a consequence of the virial theorem for an inverse-square force):
PE = −2 KE
…
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